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Urbanization and industrialization are increasing extreme weather events, causing water quantity and quality reduction. Global water scarcity impacts 32.5 % of the urban population and is growing. Brazil has also witnessed water scarcity, notably in the southeast (2014-2015) and south (2019-2020), with reservoirs dropping below 20 % capacity. Water reuse is vital for mitigating scarcity, though it presents risks due to contaminants. Risk analysis studies are crucial for evaluating contamination sources, pathways, and exposure scenarios in water reuse practices. Various methodologies, including quantitative, semi-quantitative, and qualitative analyses, can be employed. Given the uncertainty and diverse factors, qualitative methods are recommended for non-potable water reuse risk analysis. This work presents a qualitative risk analysis methodology that allows to evaluate non-potable water reuse categories. It assesses factors affecting human health and the environment, considering exposure scenarios, characteristics of the receptors, and sources of reused water. The risk analysis of water reuse was carried out focusing on agricultural reuse, considering as alternatives the irrigation of soybean and sugarcane crops. By reviewing literature, the probability of occurrence and the magnitude of impact of the risk factors were identified and rated, using an increasing relative numeric scale. This process resulted in an overall risk value for comparing agricultural irrigation alternatives. The obtained results indicate a promising risk analysis model that can be adjusted and applied to various water reuse modalities and key factors. This adaptable risk analysis model is mainly related to water treatment methods, prompting the proposal of risk control measures.

RESUMEN

Chemical oxidation using Fenton's reagent has proven to be a viable alternative to the oxidative destruction of organic pollutants in mixed waste chemicals, but the sulfate concentration in the treated liquor was still above the acceptable limits for effluent discharge. In this paper, the feasibility of sulfate removal from complex laboratory wastewaters using barium and calcium precipitation was investigated. The process was applied to different wastewater cases (two composite samples generated in different periods) in order to study the effect of the wastewater composition on the sulfate precipitation. The experiments were performed with raw and oxidized wastewater samples, and carried out according to the following steps: (1) evaluate the pH effect upon sulfate precipitation on raw wastewaters at pH range of 2-8; (2) conduct sulfate precipitation experiments on raw and oxidized wastewaters; and (3) characterize the precipitate yielded. At a concentration of 80 g L(-1), barium precipitation achieved a sulfate removal up to 61.4% while calcium precipitation provided over 99% sulfate removal in raw and oxidized wastewaters and for both samples. Calcium precipitation was chosen to be performed after Fenton's oxidation; hence this process configuration favors the production of higher quality precipitates. The results showed that, when dried at 105 degrees C, the precipitate is composed of hemidrate and anhydrous calcium sulfate ( approximately 99.8%) and trace metals ( approximately 0.2%: Fe, Cr, Mn, Co, Ag, Mg, K, Na), what makes it suitable for reuse in innumerous processes.

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RESUMEN

Fenton's process has proven to be a viable alternative for the oxidation of organic pollutants in mixed waste chemicals, with a high efficiency in the removal of heavy metals from the effluent as a side effect. However, a solid residue loaded with metals is obtained as a by-product. In this paper, the solids originating from the Fenton's oxidation of mixed waste chemicals from an academic laboratory were studied. The process was applied to different wastewater cases (two composite samples generated in different periods) in order to study the effect of their characteristics on the residues composition. Residues were evaluated and classified according to their leaching properties. In addition, a most comprehensive assessment of metal mobility in the residues was obtained by chemical speciation. The Fenton's residues were classified as hazardous according to Brazilian waste regulations. The application of the sequential dissolution procedure indicated that the metals in the Fenton's residues are mainly constituted of amorphous material (over 80%). Furthermore, the reactive fractions of the residues (exchangeable and amorphous iron oxide fractions) retain most of remaining metals. Therefore, the Fenton's residues present great potential for environmental contamination, and require an administration system and control of their final disposal.

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RESUMEN

Establishing a treatment process for practical and economic disposal of laboratory wastewaters has become an urgent environmental concern of the Department of Chemical Engineering of the Universidade Estadual de Maringá (State University of Maringá), Brazil. Fenton and related reactions are potentially useful oxidation processes for destroying toxic organic compounds in water. In these reactions, hydrogen peroxide is combined with ferrous or ferric iron in the presence or absence of light to generate hydroxyl radicals (.OH). The feasibility of Fenton's reagent to treat waste chemicals from an academic research laboratory was investigated in this study. A response surface methodology was applied to optimize the Fenton oxidation process conditions using chemical oxygen demand (COD) removal as the target parameter to optimize, and the reagent concentrations, as related to the initial concentration of organic matter in the effluent, and pH as the control factors to be optimized. Maximal COD removal (92.3%) was achieved when wastewater samples were treated at pH 4 in the presence of hydrogen peroxide and iron in the ratios [COD]:[H2O2]=1:9 and [H2O2]:[Fe2+]=4.5:1. Under these conditions, it was possible to obtain simultaneously maximal COD removal and minimal chemical sludge after treatment, which is a residue that needs further processing.

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