RESUMEN
So far, there is no validated technology for characterizing the dispersion and morphology state of carbon nanotubes (CNTs) aqueous dispersions during sonication. Taking advantage of the conductive nature of CNTs, the main hypothesis of the current study is that Electrochemical Impedance Spectroscopy (EIS) is an appropriate technique for the in-situ monitoring and qualification of the dispersion state of CNTs in aqueous media. To confirm our hypothesis, we monitored the Impedance |Z| during the sonication process as a function of type CNTs/admixtures used for the preparation of the aqueous solutions and of crucial process parameters, such as the applied sonication power and duration (i.e., sonication energy). For dispersions above the percolation threshold, a drop of |Z| by approximately seven orders of magnitude was observed, followed by a linear reduction. The dramatic change in |Z| is regarded as an indication of the formation of a conductive path or destruction of an existing one during sonication and can be used to characterize the dispersion and morphology state of CNTs. The results of the EIS provide, straightforwardly and reliably, the required information to create an optimum dispersion protocol for conductive CNT suspensions. The produced dispersions are part of research focusing on the manufacturing of cement-based composite materials with advanced thermoelectric functionalities for energy harvesting. Such dispersions are not only limited to energy harvesting applications but also to applications where functionalities are introduced through the use of conductive-based suspensions.
RESUMEN
An effective approach for an embedded piezo diagnostic layer into thick composite material is presented. The effectiveness of the approach is assessed in comparison to the surface-mounted layer. The proposed manufacturing alleviates difficulties associated with trimming edges of composites when embedding wires. The Electro-Mechanical Impedance technique is used to access the integrity of the piezoelectric sensors bonding process. Comparisons of ultrasonic guided waves are made between embedded and surface-mounted diagnostic layers and their penetration through and across the thickness of the composites. Temperature influences with the range from -40 °C up to 80 °C on embedded and surface-mounted guided waves are investigated. An investigation is carried out into the relationship between amplitude and time-of-flight with temperature at different excitation frequencies. The temperature has significant but different effects on amplitude and phase-shift of guided waves for the embedded layer compared to the surface-mounted layer. A Laser Doppler Vibrometer is used to identify the blue tack and impact damage. Both embedded and surface-mounted layers are shown to be an effective means of generating detectable wave scatter from damage.
RESUMEN
A novel lightweight diagnostic film with sensors/actuators and a multiple-path wiring option using inkjet printing was developed. The diagnostic film allows for systematic, accurate, and repeatable sensor placement. Furthermore, the film is highly flexible and adaptable for placement on complex configurations. The film can be attached to the surface of the structure through a uniform secondary boundary procedure or embedded within the composite layup during curing. The surface-mounted film can simply be peeled off for repair or replacement without scratching or damaging the part. The film offers significant weight reduction compared to other available technologies. A set of extreme temperature, altitude, and vibration environment test profiles were carried out following the Radio Technical Commission for Aeronautics (RTCA) DO-160 document to assess the durability and performance of the diagnostic film for onboard application. The diagnostic film was shown to be durable and reliable in withstanding the variable operational and harsh environmental conditions of tests representing the conditions of regional aircraft.