RESUMEN
The growing concern of aquatic heavy metal (HM) pollution is dependent on the toxic nature of its bio-available form. Thus, bio-availability is guided by the HM fractionation in water. This study was therefore conducted to evaluate the spatial impact on physicochemical fractionation of HM (Zn, Mn, Cu, and Fe) in the waters of the Hirakud reservoir in India. Speciation along different pores using a filtration technique was adopted to fractionate the HMs in water samples. The result suggests that the water of the study area is polluted with Cu (0.22-0.35 mg/L), Mn (0.15-0.23 mg/L), and Fe (1.90-3.10 mg/L) that have crossed their permissible limits while Zn (0.17-0.97 mg/L) was within the permissible standard. When studied for physical partitioning, the right dyke was comparatively more polluted than the left dyke. While the water samples were dominated by the dissolved fraction of heavy metals, it was construed that a large proportion of the HMs are in bio-available form. Further, a distinct impact of spatial variation on metal fractionation was also evident in the study with PCA revealing site-specific behaviour. Therefore, it can be concluded that multiple anthropogenic activities lead to the distribution and fractionation of HMs in water.
Asunto(s)
Monitoreo del Ambiente , Metales Pesados , Contaminantes Químicos del Agua , Metales Pesados/análisis , India , Contaminantes Químicos del Agua/análisisRESUMEN
Mining activities lead to severe particulate matter (PM) pollution that consequently has a detrimental effect on ecosystem. A study was therefore conducted in a coal mining area of Odisha, India with an objective to assess the particulate matter pollution on the basis of differential aerodynamic size (PM10 and PM2.5) of the particles, the metallic (Zn and Fe) composition, and also to evaluate their nature of deposition on two identified plant species. The results suggest a significant variation in particle and heavy metal fractions in the ambient air of different sites (p < 0.05). Fe dominated the finer particle (PM2.5) fraction while Zn dominated the coarser counterpart (PM10) in the ambient air. When evaluated for the particle and heavy metal deposition on leaf surface, Shorea robusta performed better in trapping the coarser particles (PM10) while Holarrhena floribunda was found to be an efficient scrubber of the finer particles (PM2.5). Fe deposition on surface of leaves was comparatively higher than Zn irrespective of plant species or size fractions. Therefore, it is concluded that both S. robusta and H. floribunda should be planted in a schematic manner to tackle the particulate pollution in coal mining areas.
Asunto(s)
Contaminantes Atmosféricos , Minas de Carbón , Metales Pesados , Contaminantes Atmosféricos/análisis , Monitoreo del Ambiente/métodos , Ecosistema , Biodegradación Ambiental , Material Particulado/análisis , India , Tamaño de la Partícula , Carbón MineralRESUMEN
Plant response to changing air pollution is a function of various factors including meteorology, type of pollutants, plant species, soil chemistry, and geography. However, the impact of altitude on plant behavior has received little attention to date. A study was therefore conducted to evaluate the impact of altitude on the air pollution tolerance index (APTI), heavy metal accumulation, and deposition in plant species. The results favor the hypothesis of a definite impact of altitude on biochemical and heavy metal accumulation in plants. While a significant decline (p < 0.05) in the relative water content (RWC), APTI, and heavy metal accumulation with increasing altitude was evident in the studied plant species, the behavior of ascorbic acid, leaf extract pH, chlorophyll content, and the particle heavy metal deposition was erratic and did not display any statistically significant differences. The metal accumulation index was in the following order: Ni > Zn > Cu > Pb > Cd > Co. Similarly, the particle heavy metal deposition on the leaf surface (µg/cm2) displayed significant species variability (p < 0.05) and was in the order: Cu (0.303) > Pb (0.301) > Ni (0.269) > Zn (0.241) > Cd (0.044) > Co (0.025). The accumulated heavy metal and RWC showcased a significant positive correlation with the APTI, suggesting the dominant role of RWC in the plant's tolerance against air pollution in an altitudinal gradient. Future studies on the role of micrometeorological conditions in altering APTI may be fruitful in ascertaining these postulations.
Asunto(s)
Contaminación del Aire , Metales Pesados , Altitud , Cadmio , Plomo , Monitoreo del AmbienteRESUMEN
Alteration in land use and land cover is the key factor affecting the soil carbon fractions and its distribution. A study was carried out to estimate the carbon fractions in soils of agricultural, forest and pasture lands in two different areas separated on the basis of industrial activities (spoiled and unspoiled) to get an insight on the long-term soil carbon storage potential. The results showed that the mean values of the total organic carbon (TOC) and various fractions are significantly different between the land use types (p < 0.05). Irrespective of the land uses, the forest land showed significantly higher TOC (7.97) than agricultural land (6.98) and pasture lands (6.68). Further, evaluation of carbon management index (CMI) indicated that forest lands had highest CMI value compared to the other land uses. The spoiled area had significantly higher TOC and carbon fractions than their respective counterparts in the unspoiled area (p < 0.05) due to the negative industrial impact on soil biological processes. The PCA separates the sources of different carbon fractions and revealed an association of N (nitrogen) and K (potassium) with VL (very labile) and L (labile) fractions and the association of P (phosphorous) with stable R (recalcitrant) form. Therefore, it can be inferred from the present study that alterations in land use not only result in soil quality degradation but also trigger a reduction in potential for long term soil C sequestration.