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1.
Materials (Basel) ; 16(21)2023 Nov 03.
Artículo en Inglés | MEDLINE | ID: mdl-37959625

RESUMEN

Spot welded joints play a crucial role in the construction of modern automobiles, serving as a vital method for enhancing the structural integrity, strength, and durability of the vehicle body. Taking into account spot welding process in automotive bodies, numerous defects can arise, such as insufficient weld nugget diameter. It may have evident influence on vehicle operation or even contribute to accidents on the road. Hence, there is a need for non-invasive methods that allow to assess the quality of the spot welds without compromising their structural integrity and characteristics. Thus, this study describes a novel method for assessing spot welded joints using ultrasound technology. The usage of ultrasonic surface waves is the main component of the proposed advancement. The study employed ultrasonic transducers operating at a frequency of 10 MHz and a specially designed setup for testing various spot welded samples. The parameters of the spot welding procedure and the size of the weld nugget caused differences in the ultrasonic surface waveforms that were recorded during experiments. One of the indicators of weld quality was the amplitude of the ultrasonic pulse. For low quality spot welds, the amplitude amounted to around 25% of the maximum value when using single-sided transducers. Conversely, for high-quality welds an amplitude of 90% was achieved. Depending on the size of the weld nugget, a larger or smaller amount of wave energy is transferred, which results in a smaller or larger amplitude of the ultrasonic pulse. Comparable results were obtained when employing transducers on both sides of the tested joint, as an amplitude ranging from 13% for inferior welds to 97% for superior ones was observed. This research confirmed the feasibility of employing surface waves to assess the diameter of the weld nugget accurately.

2.
Materials (Basel) ; 16(13)2023 Jun 23.
Artículo en Inglés | MEDLINE | ID: mdl-37444858

RESUMEN

This paper presents study results of laser processing of W-Cr, WCr/Cr3C2 and Cr3C2 pre-coats applied on steel substrate in the form of paste. For this study, production parameters were selected to obtain the greatest possible durability of final coatings. Laser processing was carried out using a diode laser machine with a rated power of 3 kW. The laser beam scanning speed was constant at 3 m/min, but variable laser beam powers were used: 600 W, 900 W and 1200 W. Multiple laser tracks with 60% overlapping were used. After remelting the pre-coat with a steel substrate, new coatings were obtained. Following the experiment, microstructure, microhardness, wear, corrosion resistance and chemical composition were investigated. It was found that it is possible to produce W-Cr/Cr3C2 coatings through laser processing. These coatings do not have the characteristics of a composite coating; however, increasing the reinforcing phase in the pre-coat positively affects the wear resistance and microhardness. The addition of a reinforcing phase was found to lead to a microhardness of about 750-890 HV01 for 25% and 75% Cr3C2, respectively, in comparison to coating without Cr3C2. The wear resistance of coatings reinforced by chromium carbide improved more than twofold in reference to the W-Cr coating.

3.
Materials (Basel) ; 16(14)2023 Jul 14.
Artículo en Inglés | MEDLINE | ID: mdl-37512273

RESUMEN

The paper presents study results of Stellite-6/(WC+TiC) coatings produced by laser alloying with varying contents of reinforcing phases (40%wt and 60%wt content of mixture WC+TiC). The coatings were produced on S355 steel using different laser beam power densities: 76 kW/cm2, 115 kW/cm2 and 153 kW/cm2. The coatings obtained were subjected to microhardness measurements, wear resistance tests, chemical composition analysis and microstructure observations using light microscopy and scanning electron microscopy. It was found that both types of coatings were characterized by higher microhardness and wear resistance in comparison to substrate material. The rate of solidification had an impact on the obtained results of the study.

4.
Materials (Basel) ; 15(18)2022 Sep 15.
Artículo en Inglés | MEDLINE | ID: mdl-36143727

RESUMEN

This paper presents the results of the microstructure, mechanical and physicochemical properties of coatings produced by the remelting of a VC pre-coat applied in the form of a paste on 145Cr6 steel. The remelting process was carried out using a diode laser beam. A laser device with a rated power of 3 kW was used. During these tests, a constant laser beam scanning speed of 3 m/min was used. The variable parameter was the laser beam power. Values of 500 W, 900 W and 1100 W were used. In the first stage of this study, single laser tracks were formed, and basic tests, such as on microstructure, microhardness and chemical composition, were performed. In the second stage of this study, multiple laser tracks were prepared using previously selected parameters. On such specimens, it was possible to test the same traits as for single tracks and, additionally, to perform corrosion and wear resistance tests. It was found that the obtained coatings have different properties than the base material. No primary vanadium carbides were found in the melted zone, but the proposed production method contributed to an increase in microhardness and wear resistance.

5.
Materials (Basel) ; 15(3)2022 Jan 19.
Artículo en Inglés | MEDLINE | ID: mdl-35160703

RESUMEN

This paper presents preliminary tests of the parameter analysis of the Fe/ZrC coatings production process and the obtained properties. The effects of laser beam power on the obtained microstructure, chemical composition and microhardness were investigated. The tests consisted of the production of composite coatings by laser processing of initial coatings made in the form of a paste on a steel substrate. During the tests, a diode laser with a rated power of 3 kW was used. The laser processing process was carried out using a constant scanning speed laser beam of 3 m/min and four different powers of the laser beam: 500 W, 700 W, 900 W, 1100 W. It was found that it is possible to create composite coatings on a steel surface, where the matrix is made of iron-based alloy and the reinforcing phase is ZrC carbide. It was also found that reinforcing phase content decreased as laser beam power increased. A similar relationship was found for microhardness. As laser beam power increases, the microhardness of the iron-based matrix decreases, finally reaching a value lower than the heat-affected zone. It was found that the amount of hard carbide phases in the iron-based matrix affects the total hardness of the coatings. Presented study concern Fe/ZrC coatings that have not previously been produced on steel by laser processing of precoating, which may be a new contribution in the field of metal surface engineering.

6.
Materials (Basel) ; 14(24)2021 Dec 08.
Artículo en Inglés | MEDLINE | ID: mdl-34947123

RESUMEN

The paper presents the results of studies of microstructure, mechanical and physicochemical properties of surface layers produced by laser modification of the diffusion boron layer on Monel® Alloy 400. The diffusion boron layers were produced at 950 °C for 6 h. The gas-contact method was used in an open retort furnace. The process was carried out in a powder mixture containing B4C carbide as a boron source. The next stage was the modification of the boron layer with a diode laser beam of a nominal power of 3 kW. A constant power of 1400 W of the laser beam was used. The scanning speed was variable (successively 5 m/min, 25 m/min, 50 m/min). In order to determine the best parameters, single tracks were created, after which multiple tracks were prepared using previously selected parameters. It was found that both the diffusion borided layer and the laser modified layer had better properties than the substrate material. Both these processes contributed to an increase in corrosion resistance, hardness and wear resistance. It was also found that laser modification caused a slight deterioration of the properties in comparison with the diffusion borided layer. However, the laser modification process resulted in the production of a much thicker layer.

7.
Materials (Basel) ; 14(18)2021 Sep 17.
Artículo en Inglés | MEDLINE | ID: mdl-34576591

RESUMEN

The paper presents study results of Fe/TaC metal matrix composite coatings produced on tool steel using laser processing of TaC pre-coat. The Fe/TaC coatings were produced in two steps. First, a pre-coat in the form of a paste based on tantalum carbide and water glass was made and then applied to the steel substrate. In the second step, the TaC pre-coat was remelted with steel substrate using a diode laser beam with a rated power of 3 kW. A constant scanning speed of the laser beam of 3 m/min and three types of laser beam power: 500 W, 800 W and 1100 W were applied. Tests were carried out on three different thicknesses of the TaC pre-coat: 30 µm, 60 µm and 90 µm. The influence of pre-coat thickness and laser beam power on the microstructure, chemical composition and microhardness were analyzed. A possibility of producing coatings with a characteristic composite structure was found, where the iron from the substrate became the matrix, and the introduced tantalum carbides-the reinforcing phase. It was found that too high power of the laser beam leads to complete melting of the introduced primary TaC particles. It was also found that the use of a thicker TaC pre-coat contributes to microhardness increase.

8.
Materials (Basel) ; 14(13)2021 Jul 05.
Artículo en Inglés | MEDLINE | ID: mdl-34279330

RESUMEN

Sub-zero treatment of Vanadis 6 steel resulted in a considerable reduction of retained austenite amount, refinement of martensite, enhancement of population density of carbides, and modification of precipitation behaviour. Tempering of sub-zero-treated steel led to a decrease in population density of carbides, to a further reduction of retained austenite, and to precipitation of M3C carbides, while M7C3 carbides precipitated only in the case of conventionally quenched steel. Complementary effects of these microstructural variations resulted in more noble behaviour of sub-zero-treated steel compared to the conventionally room-quenched one, and to clear inhibition of the corrosion rate at the same time.

9.
Materials (Basel) ; 13(22)2020 Nov 21.
Artículo en Inglés | MEDLINE | ID: mdl-33233406

RESUMEN

The paper presents the study results of laser processing of precoat applied on C30 steel. The precoat consisted of powder mixtures with a binder in the form of water glass. Tungsten powder, chromium, and tungsten carbide (WC) were used to produce the precoat. The laser processing was carried out using a Yb:YAG disc laser with a rated power of 1 kW. Constant producing parameters (power of laser beam, 600 W; laser beam scanning rate, 400 mm/min) were applied. Chemical composition of the precoat was a variable parameter in coating production. A mixture consisting of 50% W and 50% Cr as a metal matrix was prepared. Subsequently, WC particles in weight ratios of 25%, 50%, and 75% were added to matrix. As a result, W-Cr metal matrix composite coatings reinforced with WC particles were formed. This study focused on investigation of microstructure, microhardness, phase, and chemical composition as well as corrosion and wear resistance, of the newly formed W-Cr/WC coatings. An instrumented nanoindentation test was also used in this study. As a result of laser beam action, the newly formed coatings had an interesting microstructure and good properties which were improved in comparison to substrate material. It is anticipated that the resulting coatings, depending on the treatment parameters (e.g., W-Cr/WC powder mixture) used, can be successfully applied to metal forming or foundry tools.

10.
Materials (Basel) ; 13(15)2020 Jul 22.
Artículo en Inglés | MEDLINE | ID: mdl-32707849

RESUMEN

The paper presents study results of laser alloying of CT90 tool steel with an applied pre-coat of boron, molybdenum or a mixture of these elements. Pre-coats were applied on steel substrates in the form of a paste. The aim of the study was to investigate the microstructure, chemical and phase composition, microhardness and corrosion resistance of these newly-formed coatings. The laser alloying process was carried out using a diode laser with a nominal power of 3 kW. In this study a laser beam power of 900 W and a scanning speed of 48 mm/s were used. As a result of the laser beam action, the presence of three areas was observed in cross-sections of specimens: a remelted zone, a heat affected zone and the substrate. The properties of coatings enriched with both molybdenum and boron were better than those of the steel substrate, but only the use of a Mo-B mixture resulted in a significant improvement in microhardness and corrosion resistance.

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