RESUMEN

As one of the most widely used inorganic fine powder fillers, calcium carbonate is cheap. However, considering its poor light transmittance, it is not suitable to be added to resin matrix composites that require high light transmittance. Aluminum hydroxide has good light transmission and flame retardancy, but it is more expensive than calcium carbonate. CaCO3/Al(OH)3 composites with a core-shell structure that showed a trend toward the performance of aluminum hydroxide not only improved the surface properties of CaCO3, but also increased the added value of CaCO3. In the present paper, CaCO3/Al(OH)3 composites were successfully prepared in sodium aluminate solution via heterogeneous nucleation. Four types of calcium sources, including calcite-type precipitated calcium carbonate, vaterite-type precipitated calcium carbonate, ground calcium carbonate with two different particle sizes as the precursors and supersaturated sodium aluminate solution as the substrate, have been deeply investigated in terms of their influence on the preparation of CaCO3/Al(OH)3 composites. Results showed that the calcium carbonate precursor greatly affected the formation of CaCO3/Al(OH)3 composites. Both the precipitated calcium carbonate and the small particle ground calcium carbonate are likely to undergo anti-causticization and a complexation reaction with it to generate 3CaO·Al2O3·6H2O and 3CaO·Al2O3·CaCO3·11H2O, which go against the coating of calcium carbonate with aluminum hydroxide. Within the experimental range, the use of ground calcium carbonate with a particle size of 400-500 mesh is more suitable as a precursor for the preparation of core-shell CaCO3/Al(OH)3 composites.

RESUMEN

Many countries, such as China, today are facing the scarcity and pollution issues of freshwater resources. Suspended solids, as wastewater contaminants, may contain components such as nitrogen, phosphorus, heavy metals and pathogens that are harmful to the environment and human health, it is essential to know the size distribution regularity of the solids with a view to guiding the management of freshwater resources for sustainability. Particle size distribution (PSD) mathematical models and properties of suspended solids in a typical freshwater pond were investigated in this study. Particle size was measured using a laser particle size analyzer (measurement range: 0.01-3500 µm). The power law model and the variable-ß model were tested for their ability to fit the numeric distribution of suspended solids; Gaussian (i.e., normal) distribution and log-normal distribution models were used to evaluate the volumetric distribution of suspended solids. The results showed that: by number, about 80% of the particles contributed to only 10% of total particle volume, while the remaining 20% contributed about 90% of the total volume. For numeric distribution, the variable-ß model (R2 = 0.975 ±â€¯0.011) was better than the power law model (R2 = 0.899 ±â€¯0.033); for the volumetric distribution, the log-normal distribution model (R2 = 0.968 ±â€¯0.020) clearly outperformed the Gaussian distribution model (R2 = 0.655 ±â€¯0.093). Overall, the variable-ß model and log-normal distribution were shown to accurately describe the numerical and volumetric distribution of pond water suspended solids, respectively. PSD model parameters can be related to some compositions in the wastewater and can provide guidance for suspended solids further treatment, be it physical, biological, chemical or synthetic methods.

Asunto(s)

Agua Dulce/química , Modelos Teóricos , Aguas Residuales/química , Contaminantes Químicos del Agua/análisis , China , Monitoreo del Ambiente , Metales Pesados/análisis , Metales Pesados/química , Nitrógeno/análisis , Nitrógeno/química , Distribución Normal , Tamaño de la Partícula , Fósforo/análisis , Fósforo/química , Estanques/química , Contaminantes Químicos del Agua/química

RESUMEN

Phosphogypsum, which contains more than 90% of the calcium sulfate dehydrate (CaSO4 · 2H2O), is a kind of important renewable gypsum resources. Unlike the natural gypsum, however, phosphorus, fluorine, organic matter and other harmful impurities in phosphogypsum limit its practical use. To ascertain the existence form, content and phase distribution of trace fluoride in phosphogypsum has important theoretical values in removing trace fluoride effectively. In this present paper, the main existence form and phase distribution of trace fluoride in phosphogypsum was investigated by the combination of X-ray photoelectron spectroscopy (XPS) and Electron microprobe analysis (EMPA). The results show that trace fluoride phase mainly includes NaF, KF, CaF2, K2SiF6, Na2SiF6, Na3AlF6, K3AlF6, AlF3 · 3H2O, AlF2.3(OH)0.7 · H2O, Ca5(PO4)3F, Ca10(PO4)6F2. Among them, 4.83% of fluorine exists in the form of fluoride (NaF, KF, CaF2); Accordingly, 8.43% in the form of fluoride phosphate (Ca5(PO4)3F, Ca10(PO4)6F2); 12.21% in the form of fluorine aluminate (Na3AlF6, K3AlF6); 41.52% in the form of fluorosilicate (K2SiF6, Na2SiF6); 33.02% in the form of aluminum fluoride with crystal water (AlF3 · 3H2O, AlF2.3(OH)0.7 · H2O). In the analysis of phase constitution for trace elements in solid samples, the method of combining XPS and EMPA has more advantages. This study also provides theoretical basis for the removal of trace fluorine impurity and the effective recovery of fluorine resources.