RESUMEN
In the process of approval of active substances and authorization in the European Union and at the member state level, it must be shown by the applicant that an unacceptable risk for nontarget organisms in the aquatic environment by the active substance can be excluded. To achieve this aim, standardized models, scenarios, and agreed pesticide input parameters have to be used to calculate the exposure as defined by the FOrum for the Co-ordination of pesticide fate models and their Use (FOCUS). During a period of daily surface water sampling lasting 3.5 years, a survey was conducted among farmers in the highly vulnerable catchment of Grote Kemmelbeek in Belgium to collect agronomic data on crops, application dates, and application rates of 12 applied herbicides and one metabolite. Daily surface water concentrations for the same herbicides were measured over 2.5 years for a second, much larger but less vulnerable, catchment of Kleine Aa (KAa). A comparison of realistic worst-case predicted environmental concentrations in surface water (PECsw) according to FOCUS with measured concentrations shows that, in the GKb catchment, the PECsw was never exceeded for six substances, was exceeded on only 1-2 days for five substances, and was exceeded on 9-27 days for two substances. For the KAa catchment, the PECsw was only exceeded on two days for one compound and never for the other 12 compounds. These numbers correspond to a level of protection of the FOCUS PECsw between 100% and 97% and are much higher than the regulatory protection goal of 90%. These two case studies demonstrate the protectiveness of the FOCUS surface water approach. Integr Environ Assess Manag 2024;20:1447-1462. © 2024 Bayer AG. Integrated Environmental Assessment and Management published by Wiley Periodicals LLC on behalf of Society of Environmental Toxicology & Chemistry (SETAC).
Asunto(s)
Monitoreo del Ambiente , Herbicidas , Contaminantes Químicos del Agua , Herbicidas/análisis , Bélgica , Contaminantes Químicos del Agua/análisis , Monitoreo del Ambiente/métodos , Contaminación Química del Agua/estadística & datos numéricos , AgriculturaRESUMEN
Runoff and erosion are the most important transport pathways of water, sediment, and associated pesticides from sloped agricultural fields. This results in the loss of fertile topsoil material, nutrients, irrigation water, and plant protection products (PPP) into adjacent surface water bodies. In the European and US risk assessment for the registration of PPP, runoff and erosion are numerically calculated with the simulation Pesticide Root Zone Model (PRZM) using the US Department of Agriculture (USDA) runoff curve number (CN) concept for the water movement and the MUSS equation to quantify the sediment transfer. This work presents an evaluation of maize field trials conducted in three seasons that considered micro-dams (i.e., small earthen dams between the rows; also known as "furrow diking," "furrow damming," etc.) and/or conservation tillage (via subsoiling) as mitigation measures to investigate the effects on the reduction in runoff and erosion. Measured quantitative reductions and event-wise calculated CN are presented. Furthermore, the trials were simulated using the PRZM over the complete vegetation period and runoff CN as well as parameter values of the MUSS erosion equation (a relative adaptation of the C-factor) were inversely estimated. Compared with the control plots (i.e., conventional tillage), micro-dams or conservation tillage reduced runoff by 24%-71% or 69%-89%, and erosion by 54%-81% or 91%-98%. Based on these data, a robust case can be made to lower CN or parameters in the MUSS equation for surface water exposure scenarios to consider the effects on predicted environmental concentrations (PECs) and estimated environmental concentrations (EECs). Mean resulting CN reductions by micro-dams or conservation tillage were ascertained to be 6% (±2.5%) or 12% (±3.0%), the C-factor was reduced by a factor of 0.1 (±0.15) or 0.48 (±0.19). Example calculations show reductions in the ranges of 11%-100% for PECs and 30%-98% for EECs. Integr Environ Assess Manag 2022;18:1348-1363. © 2021 Bayer AG Crop Science. Integrated Environmental Assessment and Management published by Wiley Periodicals LLC on behalf of Society of Environmental Toxicology & Chemistry (SETAC).