RESUMEN

Gas-phase glycerol dehydration over WO3/Al2O3 catalysts was investigated. WO3 loading on γ-Al2O3 significantly affected the yield of acrolein and the catalyst with 20 wt% WO3 loading showed the highest activity. The WO3/Al2O3 catalyst with 20 wt% WO3 loading showed higher activity and durability than the other supported WO3 catalysts and zeolites. The number of Brønsted acid sites and mesopores of the WO3/Al2O3 catalyst did not decrease after the reaction, suggesting that glycerol has continuous access to Brønsted acid sites inside the mesopores of WO3/Al2O3, thereby sustaining a high rate of formation of acrolein. Dehydration under O2 flow further increased the durability of the WO3/Al2O3 catalyst, enabling the sustainable formation of acrolein. In addition, the WO3/Al2O3 catalyst with 20 wt% WO3 loading showed high activity for the dehydration of various polyols to afford the corresponding products in high yield.