RESUMEN
This paper presents a mesoscale damage model for composite materials and its validation at the coupon level by predicting scaling effects in un-notched carbon-fiber reinforced polymer (CFRP) laminates. The proposed material model presents a revised longitudinal damage law that accounts for the effect of complex 3D stress states in the prediction of onset and broadening of longitudinal compressive failure mechanisms. To predict transverse failure mechanisms of unidirectional CFRPs, this model was then combined with a 3D frictional smeared crack model. The complete mesoscale damage model was implemented in ABAQUS®/Explicit. Intralaminar damage onset and propagation were predicted using solid elements, and in-situ properties were included using different material cards according to the position and effective thickness of the plies. Delamination was captured using cohesive elements. To validate the implemented damage model, the analysis of size effects in quasi-isotropic un-notched coupons under tensile and compressive loading was compared with the test data available in the literature. Two types of scaling were addressed: sublaminate-level scaling, obtained by the repetition of the sublaminate stacking sequence, and ply-level scaling, realized by changing the effective thickness of each ply block. Validation was successfully completed as the obtained results were in agreement with the experimental findings, having an acceptable deviation from the mean experimental values.
RESUMEN
The manufacturing process in thermoset-based carbon fiber-reinforced polymers (CFRPs) usually requires a curing stage where the material is transformed from a gel state to a monolithic solid state. During the curing process, micro-residual stresses are developed in the material due to the different chemical-thermal-mechanical properties of the fiber and of the polymer, reducing the mechanical performance of the composite material compared to the nominal performance. In this study, computational micromechanics is used to analyze the micro-residual stresses development and to predict its influence on the mechanical performance of a pre-impregnated unidirectional CFRP made of T700-fibers and an aeronautical grade epoxy. The numerical model of a representative volume element (RVE) was developed in the commercial software Abaqus® and user-subroutines are used to simulate the thermo-curing process coupled with the mechanical constitutive model. Experimental characterization of the bulk resin properties and curing behavior was made to setup the models. The higher micro-residual stresses occur at the thinner fiber gaps, acting as triggers to failure propagation during mechanical loading. These micro-residual stresses achieve peak values above the yield stress of the resin 55 MPa, but without achieving damage. These micro-residual stresses reduce the transverse strength by at least 10%, while the elastic properties remain almost unaffected. The numerical results of the effective properties show a good agreement with the macro-scale experimentally measured properties at coupon level, including transverse tensile, longitudinal shear and transverse shear moduli and strengths, and minor in-plane and transverse Poisson's ratios. A sensitivity analysis was performed on the thermal expansion coefficient, chemical shrinkage, resin elastic modulus and cure temperature. All these parameters change the micro-residual stress levels and reduce the strength properties.
RESUMEN
Structural power composites stand out as a possible solution to the demands of the modern transportation system of more efficient and eco-friendly vehicles. Recent studies demonstrated the possibility to realize these components endowing high-performance composites with electrochemical properties. The aim of this paper is to present a systematic review of the recent developments on this more and more sensitive topic. Two main technologies will be covered here: (1) the integration of commercially available lithium-ion batteries in composite structures, and (2) the fabrication of carbon fiber-based multifunctional materials. The latter will be deeply analyzed, describing how the fibers and the polymeric matrices can be synergistically combined with ionic salts and cathodic materials to manufacture monolithic structural batteries. The main challenges faced by these emerging research fields are also addressed. Among them, the maximum allowable curing cycle for the embedded configuration and the realization that highly conductive structural electrolytes for the monolithic solution are noteworthy. This work also shows an overview of the multiphysics material models developed for these studies and provides a clue for a possible alternative configuration based on solid-state electrolytes.