RESUMEN
Artificial white-light production from primary red, green, and blue (RGB) colours is in high demand in the lighting, information technology, and wearable display industries, and it requires a simple device structure and efficient templates with stable luminophores. To realize efficient and stable optoelectronic devices, relevant materials and device structures need to be identified. Therefore, we report the construction of a simple hybrid white-light optoelectronic device with a single excitation source with efficient RGB colours on a stable optical platform. Emission wavelength-tunable R, G, and B quantum dots (QDs) with specific ligands and cetyltrimethylammonium chloride (CTMA)-modified DNA (CDNA) are prepared for the fabrication of QDs embedded in CDNA thin films with mixed and orthogonally stacked configurations. Fourier transform infrared, photoluminescence quantum yield (PLQY), ultraviolet (UV)-vis absorbance, photoluminescence, and electroluminescence (excited by blue and UV LEDs) spectra of the QDs embedded in CDNA thin films are analyzed to investigate their ligand attachment, luminescence efficiency, optical excitation, spectral emission, and hybrid white-light properties. In addition, the dispersion and photostability of QDs in the CDNA matrix were analyzed. The colour rendering index (CRI) values and colour gamut of the QDs embedded in CDNA thin films are studied for evaluating the light quality. The results show that the ligands on the QDs enhance PLQY up to 95 and 25% in liquid and solid phases, respectively. The optical properties of the QDs in the CDNA thin films are not significantly affected by phase changes, which implies the effective hosting of QDs within CDNA. The CRI values of the mixed and stacked configuration-dependent QDs embedded in CDNA thin films are 21 and 80%, respectively, which suggest the relatively stronger self-absorption of R QDs in the mixed configuration than in the stacked configuration. In addition, CRI values and colour gamut are affected by different R, G, and B QD concentrations in CDNA. These findings are important for solid-state lighting, information display systems, flexible displays, and wearable displays.
RESUMEN
To be useful in optoelectronic devices and sensors, a platform comprising stable fluorescence materials is essential. Here we constructed quantum dots (QDs) embedded DNA thin films which aims for stable fluorescence through the stabilization of QDs in the high aspect ratio salmon DNA (SDNA) matrix. Also for maximum luminescence, different concentration and configurations of core- and core/alloy/shell-type QDs were embedded within SDNA. The QD-SDNA thin films were constructed by drop-casting and investigated their optoelectronic properties. The infrared, UV-visible and photoluminescence (PL) spectroscopies confirm the embedment of QDs in the SDNA matrix. Absolute PL quantum yield of the QD-SDNA thin film shows the ~70% boost due to SDNA matrix compared to QDs alone in aqueous phase. The linear increase of PL photon counts from few to order of 5 while increasing [QD] reveals the non-aggregation of QDs within SDNA matrix. These systematic studies on the QD structure, absorbance, and concentration- and thickness-dependent optoelectronic characteristics demonstrate the novel properties of the QD-SDNA thin film. Consequently, the SDNA thin films were suggested to utilize for the generalised optical environments, which has the potential as a matrix for light conversion and harvesting nano-bio material as well as for super resolution bioimaging- and biophotonics-based sensors.