RESUMEN

This paper describes the process of producing chemiresistors based on hybrid nanostructures obtained from graphene and conducting polymers. The technology of graphene presumed the following: dispersion and support stabilization based on the chemical vapor deposition technique; transfer of the graphene to the substrate by spin-coating of polymethyl methacrylate; and thermal treatment and electrochemical delamination. For the process at T = 950 °C, a better settlement of the grains was noticed, with the formation of layers predominantly characterized by peaks and not by depressions. The technology for obtaining hybrid nanostructures from graphene and conducting polymers was drop-casting, with solutions of Poly(3-hexylthiophene (P3HT) and Poly[(9,9-dioctylfluorenyl-2,7-diyl)-co-bithiophene] (F8T2). In the case of F8T2, compared to P3HT, a 10 times larger dimension of grain size and about 7 times larger distances between the peak clusters were noticed. To generate chemiresistors from graphene-polymer structures, an ink-jet printer was used, and the metallization was made with commercial copper ink for printed electronics, leading to a structure of a resistor with an active surface of about 1 cm2. Experimental calibration curves were plotted for both sensing structures, for a domain of CH4 of up to 1000 ppm concentration in air. A linearity of the curve for the low concentration of CH4 was noticed for the graphene structure with F8T2, presenting a sensitivity of about 6 times higher compared with the graphene structure with P3HT, which makes the sensing structure of graphene with F8T2 more feasible and reliable for the medical application of irritable bowel syndrome evaluation.

Asunto(s)

Grafito , Síndrome del Colon Irritable , Metano , Nanoestructuras , Polímeros , Grafito/química , Nanoestructuras/química , Polímeros/química , Metano/química , Síndrome del Colon Irritable/metabolismo , Humanos , Pruebas Respiratorias/métodos , Tiofenos/química , Conductividad Eléctrica

RESUMEN

This paper presents the obtaining and characterization of recycled polypropylene/strontium ferrite (PP/SrFe12O19) polymer composite materials with applications in the electromagnetic shielding of vehicle interiors (mainly automotive electronics-carcasses) from the electromagnetic radiation emitted mainly by exterior sources-electrical lines and supply sources-in terms of the development of the new electrical vehicles. With this aim, suitable polymer composite materials were developed using SrFe12O19 filler in two forms (powder and concentrate). The recycled PP polymer and composite materials with a PP/SrFe12O19 weight ratio of 75/25 and 70/30 were obtained in two stages, i.e., pellets by extrusion and samples for testing through a melt injection process. The characterization of the obtained materials took into account the requirements imposed by the desired applications. It consisted of determining the mechanical and dielectric properties, and microstructure analyses, along with the determination of the resistance to the action of a temperature of 70 °C, which is higher than the temperatures created during the summer inside vehicles. The performance of these materials as electromagnetic shields was assessed through functional tests consisting of the determination of magnetic permeability and the estimation of the electromagnetic shielding efficiency (SE). The obtained results confirmed the improvement of the mechanical, dielectric, and magnetic properties of the PP/SrFe12O19 composites compared to the selected PP polymers. It is also found that all the composite materials exhibited reflective shielding properties (SER from -71.5 dB to -56.7 dB), with very little absorption shielding. The most performant material was the composite made of PP/SrFe12O19 powder with a weight ratio of 70/30. The promising results recommend this composite material for potential use in automotive shielding applications against electromagnetic pollution.