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1.
J Environ Manage ; 370: 122797, 2024 Oct 08.
Artículo en Inglés | MEDLINE | ID: mdl-39383744

RESUMEN

Glyphosate (GLY), a globally-used organophosphate herbicide, is frequently detected in various environmental matrices, including water, prompting significant attention due to its persistence and potential ecological impacts. In light of this environmental concern, innovative remediation strategies are warranted. This study utilized Serratia sp. AC-11 isolated from a tropical peatland as a biocatalyst in a microbial fuel cell (MFC) coupled with a homogeneous electron-Fenton (EF) process to degrade glyphosate in aqueous medium. After coupling the processes with a resistance of 100 Ω, an output voltage value of 0.64 V was obtained and maintained stable throughout the experiment. A bacterial biofilm of Serratia sp. AC-11 was formed on the carbon felt electrode, confirmed by attenuated total reflectance-Fourier transformed infrared (ATR-FTIR) and scanning electron microscopy with energy dispersive spectroscopy (SEM-EDS). In the anodic chamber, the GLY biodegradation rate was 100% after 48 h of experimentation, with aminomethylphosphonic acid (AMPA) remaining in the solution. In the cathodic chamber, the GLY degradation rate for the EF process was 69.5% after 48 h experimentation, with almost all of the AMPA degraded by the in situ generated hydroxyl radicals. In conclusion, the results demonstrated that Serratia sp. AC-11 not only catalyzed the biodegradation of glyphosate but also facilitated the generation of electrons for subsequent transfer to initiate the EF reaction to degrade glyphosate. This dual functionality emphasizes the unique capabilities of Serratia sp. AC-11, it as an electrogenic microorganism with application in innovative bioelectrochemical processes, and highlighting its role in sustainable strategies for environmental remediation.

2.
Phys Chem Chem Phys ; 26(16): 12799-12805, 2024 Apr 24.
Artículo en Inglés | MEDLINE | ID: mdl-38619871

RESUMEN

Isothiazolinones represent a class of heterocyclic compounds widely used in various applications, including as biocides in cosmetics, detergents, and paints, as well as in industrial wastewater treatment. Indeed, the presence of isothiazolinones in the environment and their associated potential health hazards have raised significant concerns. In this study, a non-adiabatic dynamics investigation was conducted using state-of-the-art methodologies to explore the photochemistry of isothiazolinones. A simplified model, isothiazol-3(2H)-one (ISO), was employed to represent this compound class. The study validated the model and demonstrated that ISO can return to its ground state through the cleavage of the S-N or S-C bonds, with no significant energy barrier observed. Non-adiabatic dynamics simulations provided insights into the time scales and detailed processes of isothiazolinone photodissociation. The preferred route for deactivation was found to be the cleavage of the S-N bond. This research enhances our understanding of the photodeactivation processes of isothiazolinones and their potential environmental impact.

3.
Nursing (Ed. bras., Impr.) ; 27(309): 10157-10160, mar.2024. tab.
Artículo en Inglés, Portugués | LILACS, BDENF - Enfermería | ID: biblio-1556467

RESUMEN

A comunicação entre pais e seus filhos no período da adolescência é fundamental para propor uma estrutura psicológica, na qual pode-se permitir que o adolescente desenvolva uma autoestima forte e independente. Objetivo: identificar por meio de literatura o comportamento autodestrutivo em adolescentes que utilizam redes sociais e jogos digitais de modo demasiado. Método: Trata-se de um estudo de cunho exploratório com intuito caracterizado por meio de revisão bibliográfica, realizada através do Google Acadêmico, Fio Cruz (Fundação Oswaldo Cruz), Biblioteca Virtual em Saúde (BVS), utilizando os uni termos: "COMPORTAMENTOS AUTODESTRUTIVOS NA ADOLESCENCIA", pesquisado apenas no idioma português," ordenado por "data" de 2002 até maio de 2023. Resultado: Mediante as bases pesquisadas forem elegíveis (22) artigos, (2) revistas e (1) livro após os critérios estabelecidos ficaram apenas 05 artigos. Conclusão: Cabe aos profissionais da saúde bem como a equipe de enfermagem, seja na atenção primaria ou dentro do ambiente hospitalar estarem preparados e capacitados para prestar uma assistência de qualidade, realizar o acolhimento e uma escuta terapêutica de forma mais positiva.(AU)


Communication between parents and their children during adolescence is fundamental to propose a psychological structure in which adolescents can develop a strong and independent self-esteem. Objective: to identify, through literature, self-destructive behavior in adolescents who use social networks and digital games too much. Method: This is an exploratory study with a purpose characterized by a bibliographical review, carried out through Google Scholar, Fio Cruz (Oswaldo Cruz Foundation), Virtual Health Library (VHL), using the uni terms: "SELF-DESTRUCTIVE BEHAVIORS NA ADOLESCENCIA", searched only in Portuguese," sorted by "date" from 2002 to May 2023. Result: According to the searched databases, (22) articles, (2) magazines and (1) book were eligible after the established criteria. only 05 articles. Conclusion: It is up to health professionals, as well as the nursing team, whether in primary care or within the hospital environment, to be prepared and qualified to provide quality care, embracement and therapeutic listening in a more positive way.(AU)


La comunicación entre padres e hijos durante la adolescencia es fundamental para proponer una estructura psicológica en la que los adolescentes puedan desarrollar una autoestima fuerte e independiente. Objetivo: identificar, a través de la literatura, conductas autodestructivas en adolescentes que utilizan demasiado las redes sociales y los juegos digitales. Método: Se trata de un estudio exploratorio con finalidad caracterizada por una revisión bibliográfica, realizada a través de Google Scholar, Fio Cruz (Fundación Oswaldo Cruz), Biblioteca Virtual en Salud (BVS), utilizando los términos uni: "CONDUCTAS AUTODESTRUCTIVAS EN LA ADOLESCENCIA" , buscado solo en portugués", ordenados por "fecha" de 2002 a mayo de 2023. Resultado: De acuerdo con las bases de datos buscadas, (22) artículos, (2) revistas y (1) libro fueron elegibles después de los criterios establecidos. sólo 05 artículos. Conclusión: Corresponde a los profesionales de la salud, así como al equipo de enfermería, ya sea en la atención primaria o en el ámbito hospitalario, estar preparados y calificados para brindar un cuidado de calidad, acogida y escucha terapéutica de forma más positiva.(AU)


Asunto(s)
Masculino , Femenino , Adolescente , Conducta , Adolescente , Conducta Autodestructiva , Redes Sociales en Línea
4.
Psychol Res Behav Manag ; 17: 467-483, 2024.
Artículo en Inglés | MEDLINE | ID: mdl-38371713

RESUMEN

Background: Previous research has suggested that manipulation and callousness are central to Dark Triad traits, but it has not identified which specific manifestations are expressed across various countries. Objective: This study aimed to identify the core and overlapping manifestations of Dark Triad traits across 10 countries. Methods: We used the Short Dark Triad (SD3) scale and assessed a sample of 8093 participants (59.7% women, M(age) = 32.68 years). For graphical representation, the spinglass algorithm was applied to understand the cluster distribution among Machiavellianism, psychopathy, and subclinical narcissism traits. Centrality indices were used to identify the most influential items, and the clique-percolation algorithm was employed to detect shared attributes among multiple Dark Triad items. Results: Straightforward SD3-21 items demonstrated better interpretability as aversive traits within the broader system. Items with higher centrality values were those related to short-term verbal manipulation from the psychopathy domain, clever manipulation, strategic revenge-seeking from Machiavellianism, and narcissistic motivations for connecting with significant individuals. The most predicted items were linked to planned revenge, using information against others from Machiavellianism, short-term psychopathic verbal manipulation, and narcissistic belief of specialness based on external validation. Items like short-term verbal manipulation had overlaps with both psychopathy and narcissism clusters, while clever manipulation overlapped with Machiavellianism and psychopathy. Conclusion: This cross-cultural study highlights the central role of verbal manipulation within the Dark Triad traits, along with identifying overlapping items among traits measured using straightforward SD3 scale items. In line with our findings, future research that incorporates a wide range of cultural contexts is encouraged to establish the consistency of these findings with the SD3 Scale or alternative measures.

5.
Arch Orthop Trauma Surg ; 144(4): 1485-1490, 2024 Apr.
Artículo en Inglés | MEDLINE | ID: mdl-38285221

RESUMEN

PURPOSE: Plantar fasciitis (PF) is a main source of heel pain, and only about one-third of patients have bilateral symptomatic involvement, although age, body mass index (BMI), and physical activities are known risk factors. The high prevalence of unilateral involvement is poorly understood. We aimed to assess the potential association between PF and the leg length discrepancy (LLD) in unilateral PF. METHODS: A transversal case-control study was conducted from January 2019 to December 2020, including 120 participants allocated to two groups matched by BMI and sex: cases (with a diagnosis of PF; 50 ± 13 years) and control (without foot pain; 40 ± 15 years). For both groups, a difference greater than 0.64 cm in the scanometry determined the criteria for the presence of LLD. RESULTS: The multivariate logistic regression analysis showed an independent association of PF only with age (p < 0.001), and no association with LLD. We did not observe differences in the mean discrepancy (1.37 ± 0.83 cm in the PF group in comparison with 1.13 ± 0.37 cm in the control group, [p > 0.05]) or in the prevalence of LLD between groups (48% [n = 29] in the PF group compared with 42% [n = 25] in the control group, [p > 0.05]). In the PF group, 80% of the participants reported unilateral pain. We observed a higher prevalence of pain in the shorter limb (p < 0.05). CONCLUSION: Age was the only factor associated with the diagnosis of PF when groups were matched by sex and BMI. LLD was not an independent factor associated with the diagnosis of PF. However, when PF is unilateral, the shorter limb is more affected with 70% of prevalence. LEVEL OF EVIDENCE: Level III, case-control.


Asunto(s)
Fascitis Plantar , Humanos , Fascitis Plantar/diagnóstico , Fascitis Plantar/epidemiología , Fascitis Plantar/etiología , Estudios de Casos y Controles , Pierna , Dolor , Diferencia de Longitud de las Piernas/epidemiología , Diferencia de Longitud de las Piernas/etiología , Factores de Riesgo
8.
Estud. Psicol. (Campinas, Online) ; 41: e210022, 2024. tab, graf
Artículo en Inglés | LILACS-Express | LILACS, Index Psicología - Revistas | ID: biblio-1569177

RESUMEN

Abstract Objective of this study was to, based on a theoretical model, verify the associations between the variables passion, affect, satisfaction with life, and distress, the predictive power of the different types of passion on the perception of positive and negative affect, and the effect of this relation against the evaluation of psychological well-being and distress. Method Three hundred and fifty-nine participants aged between 18 and 70 years (M = 36.60; SD = 11.90) answered a sociodemographic questionnaire, and the Passion, Positive and Negative Affect Schedule, Satisfaction with Life, and the Kessler Psychological Distress Scales. Data were analyzed using correlation coefficients and structural equation modeling. Results The adequacy of the proposed model was estimated with satisfactory fit indices and positive relations between Harmonious Passion, Positive Affect, and Satisfaction with Life. Conclusion The results suggest that Harmonious Passion contributes to coping with suffering and negative experiences, such as those experienced in the pandemic moment.


Resumo Objetivo Verificar as associações entre as variáveis paixão, afetos, satisfação com a vida e distresse, o poder preditivo dos diferentes tipos de paixão sobre a percepção de afetos positivos e negativos, e o efeito desta relação frente a avaliação de bem-estar psicológico e distresse, partindo de um modelo teórico. Método Participaram 359 sujeitos, com idades entre 18 e 70 anos (M = 36,60; DP = 11,90) que responderam ao questionário sociodemográfico, Escalas de Paixão, Afetos Positivos e Negativos, Satisfação com a Vida e Distresse Psicológico de Kessler. Os dados foram analisados por meio de coeficientes de correlação e modelagem de equações estruturais. Resultados A adequação do modelo proposto foi verificada com índices ajustes satisfatórios e relações positivas entre Paixão Harmoniosa, Afetos Positivos e Satisfação com a Vida. Conclusão Os resultados sugerem que a Paixão Harmoniosa contribui para o enfrentamento do sofrimento e de experiências negativas, como os experimentados no momento pandêmico.

9.
J Comp Pathol, v. 211, p. 21-25, mai. 2024
Artículo en Inglés | Sec. Est. Saúde SP, SESSP-IBPROD, Sec. Est. Saúde SP | ID: bud-5398

RESUMEN

Ichthyophthirius multifiliis, the causative agent of white spot disease, is a ciliated protozoan parasite that infects freshwater fish and induces high mortality. Outbreaks occur both in natural and production sites. The aim of the present study was to describe the lesions caused by chronic infection by I. multifiliis in goldfish (Carassius auratus) from an ornamental fish farm, highlighting important ultrastructural aspects of this protozoan. Damaged skin and gills, collected from fish with white or ulcerative skin lesions, were routinely processed for histological analysis and transmission electron microscopy. The parasitic forms present in the skin were associated with an inflammatory infiltrate consisting of macrophages, lymphocytes and other polymorphonuclear cells. The lesions associated with the presence of the parasite were organized in the form of granulomas, with macrophages in the layers closest to the parasites. A trophont-thickened membrane and induction of granulomatous inflammation were identified in this study as mechanisms for evasion of the immune response. We concluded that the presence of I. multifiliis trophonts resulted in the formation of granulomatous inflammation, whether associated or not with pathogen lysis, suggesting that the parasite can use an inflammatory response to evade the immune response.

10.
Artículo en Portugués | LILACS-Express | LILACS | ID: biblio-1574598

RESUMEN

A autorregulação emocional frente a eventos tristes é essencial nas diferentes fases do desenvolvimento humano, principalmente ao tratar-se de crianças e adolescentes, uma vez que diferentes estratégias de autorregulação podem ser fatores protetivos a transtornos mentais como a depressão. Dado a existência da Escala de Autorregulação Emocional-Infantojuvenil (EARE-IJ) para mensurar tais eventos, este artigo tem como objetivo apresentar a versão revisada do instrumento, com o intuito de aprimorá-la, buscar evidências de validade baseadas na estrutura interna e índices de fidedignidade. Responderam ao instrumento 299 crianças e adolescentes, com idades de 10 até 16 anos (M= 12,20; DP= 1,36), de modo que foram testados diferentes modelos de análise fatorial confirmatória, coeficientes de confiabilidade e um modelo de invariância para a variável sexo. Os resultados acumulam evidências favoráveis para o instrumento em sua nova versão, passando a ser conhecida como Escala de Desregulação Emocional Infantojuvenil (EDEIJ). Além de indicarem que o instrumento é capaz de avaliar crianças e adolescentes com diferentes níveis de desregulação emocional, bem como possui invariância configural e métrica. Conclui-se que a ferramenta é eficiente para realizar o rastreio de estratégias de autorregulação emocional em crianças e adolescentes.


La autorregulación emocional ante eventos tristes es fundamental en diferentes etapas del desarrollo humano, especialmente cuando se trata de niños y adolescentes, ya que diferentes estrategias de autorregulación pueden ser factores protectores de trastornos mentales como la depresión. Dada la existencia de la Escala de Autorregulación Emocional-Niños y Jóvenes (EARE-IJ) para medir tales eventos, este artículo tiene como objetivo presentar la versión revisada del instrumento para mejorarlo, buscando evidencia de validez basada en la estructura e índices de confiabilidad. El instrumento fue respondido por 299 niños y adolescentes, de 10 a 16 años (M = 12.20; DE = 1.36). Se utilizaron diferentes modelos de análisis factorial confirmatorio, coeficientes de confiabilidad y un modelo de invariancia para la variable sexo. Los resultados acumulan evidencias favorables para el instrumento en su nueva versión, que se conoce como Escala de Desregulación Emocional Infantil y Juvenil (EDEIJ). Además de indicar que el instrumento es capaz de evaluar a niños y adolescentes con diferentes niveles de desregulación emocional, tiene invariancia configural y métrica. Se concluye que la herramienta es eficaz para realizar el cribado de estrategias de autorregulación emocional en niños y adolescentes.


Emotional self-regulation when confronted with sad events is essential in different stages of human development, especially when it comes to children and adolescents, as different self-regulation strategies can serve as protective factors against mental disorders such as depression. This article aims to present the revised version of the Emotional Self-Regulation Scale Child and Adolescent (EARE-IJ, Escala de Autorregulação Emocional-Infantojuvenil), an instrument for measuring emotional self-regulation strategies toward sad events, with the purpose of improving it, searching for validity evidence based on the internal structure and reliability indices. The instrument was answered by 299 children and adolescents, aged 10 to 16 years (M= 12.20; SD= 1.36), and different models of confirmatory factor analysis, reliability coefficients, and an invariance model for the sex variable were tested. The results provide accumulating evidence in favor of the instrument in its new version, now known as the Emotional Dysregulation Scale Child and Adolescent (EDEIJ, Escala de Desregulação Emocional Infantojuvenil). The results also indicate that the instrument can evaluate children and adolescents with different levels of emotional dysregulation, while demonstrating configural and metric invariance. In conclusion, it is found that the tool is efficient in screening emotional self-regulation strategies in children and adolescents.

11.
Rev Bras Ortop (Sao Paulo) ; 58(5): e734-e741, 2023 Oct.
Artículo en Inglés | MEDLINE | ID: mdl-37908520

RESUMEN

Objective To provide a current overview of the Bristow-Latarjet surgery in Brazil. Materials and Methods This cross-sectional study was based on an electronic questionnaire with 26 items, which was sent to active members of the Brazilian Society of Shoulder and Elbow Surgery (Sociedade Brasileira de Cirurgia do Ombro e Cotovelo, SBCOC, in Portuguese). The questionnaire addressed training, surgical technique, complications, and postoperative management. Results We sent the questionnaire to 845 specialists from April 20 to May 12, 2021, and 310 of them answered i in full. During their specialization, most specialists participated in up to ten Bristow-Latarjet procedures. The most frequent complication was graft fracture, while the most common technical difficulty was screw positioning. In total, 50.6% and 73.9% reported having experienced intraoperative and postoperative complications respectively; 57.1% declared performing subscapularis suture; 99.7% indicated postoperative immobilization; and 61.9% considered graft consolidation fundamental. Conclusion Most specialists participated in up to ten Bristow-Latarjet procedures during the specialization, but 13.5% of them graduated without participating in the surgery. The most frequent complication was graft fracture. The most common technical difficulty was screw positioning. Most participants prefer postoperative immobilization since they believe graft consolidation is essential to resume the practiced of sports. The highest complication rate occurred with specialists who have obtained their titles 11 to 15 years ago. In Brazil, the Southeast region is the largest producer of specialists and has the highest concentration of these professionals.

12.
Animals (Basel) ; 13(20)2023 Oct 14.
Artículo en Inglés | MEDLINE | ID: mdl-37893939

RESUMEN

An 8-week trial was performed to evaluate the influence of docosahexaenoic (DHA) and eicosapentaenoic acid (EPA) ratios and temperature on the fatty acid (FA) metabolism and liver morphology of Epinephelus marginatus. A basal diet was manufactured, and DHA (D1:0.5%; D2:0.75%; D3:1%; and D4:1.5%) and EPA (D1:1.0%; D2:0.75%; D3:0.5%; and D4:0%) levels were added. E. marginatus were kept in twelve tanks with a lower temperature (LT, 23.17 ± 0.12 °C) and twelve with a higher temperature (HT, 28.63 ± 0.06 °C). The DHA/EPA ratio did not affect performance, regardless of the temperature, but the animals fed with the D4 diet showed better growth at HT. A higher lipid deposition and a large lipid vacuole area in the hepatocytes at HT were observed, regardless of the diet. Triacylglycerol (TG) in reflected the diet FA profile mainly in the muscle and liver, whereas the phospholipid (PL) was less influenced by the diet. The same DHA content in the TG fraction of muscle (D3 and D4) were observed at LT; however, only the DHA/EPA ratio of D4 could be differentially stored in the TG fraction of muscle (HT). Monounsaturated and polyunsaturated FA increased in the PL of the eyes at HT, whereas saturated FA was reduced in the TG and PL fractions at LT. These results evidence the importance of temperature and a balanced DHA/EPA ratio in the diet of marine fish.

13.
Genes (Basel) ; 14(10)2023 10 04.
Artículo en Inglés | MEDLINE | ID: mdl-37895255

RESUMEN

Lung cancer is a highly aggressive neoplasm and, despite the development of recent therapies, tumor progression and recurrence following the initial response remains unsolved. Several questions remain unanswered about non-small cell lung cancer (NSCLC): (1) Which patients will actually benefit from therapy? (2) What are the predictive factors of response to MAbs and TKIs? (3) What are the best combination strategies with conventional treatments or new antineoplastic drugs? To answer these questions, an integrative literature review was carried out, searching articles in PUBMED, NCBI-PMC, Google Academic, and others. Here, we will examine the molecular genetics of lung cancer, emphasizing NSCLC, and delineate the primary categories of inhibitors based on their molecular targets, alongside the main treatment alternatives depending on the type of acquired resistance. We highlighted new therapies based on epigenetic information and a single-cell approach as a potential source of new biomarkers. The current and future of NSCLC management hinges upon genotyping correct prognostic markers, as well as on the evolution of precision medicine, which guarantees a tailored drug combination with precise targeting.


Asunto(s)
Carcinoma de Pulmón de Células no Pequeñas , Neoplasias Pulmonares , Humanos , Carcinoma de Pulmón de Células no Pequeñas/tratamiento farmacológico , Carcinoma de Pulmón de Células no Pequeñas/genética , Carcinoma de Pulmón de Células no Pequeñas/metabolismo , Neoplasias Pulmonares/diagnóstico , Neoplasias Pulmonares/tratamiento farmacológico , Neoplasias Pulmonares/genética , Pronóstico , Resistencia a Antineoplásicos/genética , Receptores ErbB/genética , Inhibidores de Proteínas Quinasas/farmacología , Mutación
14.
Psico USF ; 28(4): 651-667, Oct.-Dec. 2023. ilus, tab
Artículo en Inglés | LILACS, Index Psicología - Revistas | ID: biblio-1529177

RESUMEN

Controlling acquiescence bias typically involves the application of positive and negative keyed items. However, little is known about the effect of balancing positive and negative items on bias control. The aim of this study was to compare three Confirmatory Factor Analysis models (without control, MIMIC, and Random Intercept) to recover the factor structure of unbalanced and balanced instruments, using simulated and real data (from an instrument that assesses Personality). By controlling for acquiescence, the results indicated that the performance of balanced scales was better than that of unbalanced scales, as well as in the absence of control for response bias, when considering balanced and unbalanced scales. Thus, this research suggests the possibility of controlling acquiescence through balanced instruments associated with the use of statistical methods in modeling.(AU)


O controle do viés de aquiescência normalmente envolve a aplicação de itens positivos e negativos. Contudo, pouco se sabe sobre o efeito do balanceamento entre itens positivos e negativos sobre o controle do viés. O objetivo deste estudo foi comparar três modelos de Análise Fatorial Confirmatória (sem controle, MIMIC e Intercepto Randômico) para recuperar a estrutura fatorial de instrumentos desbalanceados e balanceados, a partir de dados simulados e reais (procedentes de um instrumento que avalia Personalidade). Mediante o controle da aquiescência, os resultados indicaram que a performance de escalas balanceadas foi melhor do que de escalas desbalanceadas, bem como na ausência de controle desse viés de resposta, ao considerar as escalas balanceadas e desbalanceadas. Dessa maneira, esta pesquisa aponta para a possibilidade de controle de aquiescência por meio de instrumentos balanceados associada ao uso dos métodos estatísticos na modelagem.(AU)


El control del sesgo de aquiescencia involucra la aplicación de ítems positivos y negativos. Sin embargo, el efecto del equilibrio entre ítems positivos y negativos en el control del sesgo sigue siendo una pregunta abierta. En este sentido, el objetivo de este estudio fue comparar tres modelos de Análisis Factorial Confirmatorio (sin control, MIMIC e Intercepto Aleatorio) para recuperar la estructura factorial de instrumentos balanceados y desbalanceados, a partir de datos simulados y reales (a partir de un instrumento que evalúa personalidad). El control de este sesgo de respuesta indicó que el desempeño de escalas balanceadas fue mejor que el de escalas desbalanceadas, así como en la ausencia del control de la aquiescencia, al considerar escalas balanceadas y desbalanceadas. Por lo tanto, esta investigación sugiere la posibilidad de controlar este sesgo de respuesta por medio de instrumentos balanceados asociados con el uso de métodos estadísticos modelado.(AU)


Asunto(s)
Humanos , Masculino , Femenino , Adolescente , Adulto , Persona de Mediana Edad , Anciano , Adulto Joven , Inventario de Personalidad , Análisis Factorial , Modelos Estadísticos , Correlación de Datos
15.
ChemSusChem ; 16(23): e202300971, 2023 Dec 07.
Artículo en Inglés | MEDLINE | ID: mdl-37681317

RESUMEN

The zwitterions resulting from the covalent attachment of 3- or 4-hydroxy benzene to the 1,3-dimethylimidazolium cation represent basic compounds (pKa of 8.68 and 8.99 in aqueous solutions, respectively) that chemisorb in aqueous solutions 0.58 mol/mol of carbon dioxide at 1.3 bar (absolute) and 40 °C. Equimolar amounts of chemisorbed CO2 in these solutions are obtained at 10 bar and 40 °C. Chemisorption takes place through the formation of bicarbonate in the aqueous solution using imidazolium-containing phenolate. CO2 is liberated by simple pressure relief and heating, regenerating the base. The enthalpy of absorption was estimated to be -38 kJ/mol, which is about 30 % lower than the enthalpy of industrially employed aqueous solutions of MDEA (estimated at -53 kJ/mol using the same experimental apparatus). The physisorption of CO2 becomes relevant at higher pressures (>10 bar) in these aqueous solutions. Combined physio- and chemisorption of up to 1.3 mol/mol at 40 bar and 40 °C can be attained with these aqueous zwitterionic solutions that are thermally stable and can be recycled at least 20 times.

16.
Behav Sci (Basel) ; 13(9)2023 Sep 18.
Artículo en Inglés | MEDLINE | ID: mdl-37754056

RESUMEN

Substance abuse can be used as a coping strategy to manage stress related to academic activities and is a risk-taking behavior that is also associated with people with higher levels of the Dark Tetrad personality traits. Our study aimed to investigate the association between substance abuse and the Dark Tetrad in students in health and non-health sciences fields. Our sample was composed of 174 college students between 18 and 58 years old (M = 25.60; SD = 9.14). Students completed self-report psychopathy, narcissism, Machiavellianism, sadism, and substance use scales. Results suggest that men consumed more substances and scored higher on the Dark Tetrad than women. Also, when comparing fields, men from health sciences tended to score higher on dark personality traits. These results emphasize the potential risk factors associated with dark personality traits and the consumption of licit and illicit substances by college students, highlighting the need for further studies with this population and the impact of these behaviors and characteristics on future professional practice.

17.
Rev. Bras. Ortop. (Online) ; 58(5): 734-741, Sept.-Oct. 2023. tab, graf
Artículo en Inglés | LILACS | ID: biblio-1529940

RESUMEN

Abstract Objective To provide a current overview of the Bristow-Latarjet surgery in Brazil. Materials and MethodsThis cross-sectional study was based on an electronic questionnaire with 26 items, which was sent to active members of the Brazilian Society of Shoulder and Elbow Surgery (Sociedade Brasileira de Cirurgia do Ombro e Cotovelo, SBCOC, in Portuguese). The questionnaire addressed training, surgical technique, complications, and postoperative management. Results We sent the questionnaire to 845 specialists from April 20 to May 12, 2021, and 310 of them answered i in full. During their specialization, most specialists participated in up to ten Bristow-Latarjet procedures. The most frequent complication was graft fracture, while the most common technical difficulty was screw positioning. In total, 50.6% and 73.9% reported having experienced intraoperative and postoperative complications respectively; 57.1% declared performing subscapularis suture; 99.7% indicated postoperative immobilization; and 61.9% considered graft consolidation fundamental. Conclusion Most specialists participated in up to ten Bristow-Latarjet procedures during the specialization, but 13.5% of them graduated without participating in the surgery. The most frequent complication was graft fracture. The most common technical difficulty was screw positioning. Most participants prefer postoperative immobilization since they believe graft consolidation is essential to resume the practiced of sports. The highest complication rate occurred with specialists who have obtained their titles 11 to 15 years ago. In Brazil, the Southeast region is the largest producer of specialists and has the highest concentration of these professionals.


Resumo Objetivo Traçar um panorama atual da cirurgia de Bristow-Latarjet no Brasil. Materiais e Métodos Estudo transversal no qual um questionário eletrônico com 26 perguntas sobre aspectos de formação, técnica cirúrgica, complicações e manejo pós-cirúrgico foi enviado a membros ativos da Sociedade Brasileira de Cirurgia do Ombro e Cotovelo (SBCOC). Resultados Entre 20 de abril e 12 de maio de 2021, o questionário foi enviado a 845 especialistas, e obteve-se 310 respostas completas. Durante a especialização, a maior parte dos especialistas participou de até dez procedimentos de Bristow-Latarjet. A complicação mais frequente foi a fratura do enxerto, e a dificuldade técnica, o posicionamento dos parafusos. Ao todo, 50,6% já tiveram complicações no intraoperatório; 73,9% já tiveram complicações no pós-operatório; 57,1% fazem a sutura do subescapular; 99,7% indicam a imobilização no pós-operatório; e 61,9% consideram a consolidação do enxerto fundamental. Conclusão A maior parte dos especialistas participou de até dez procedimentos de Bristow-Latarjet durante a especialização, mas 13,5% se formaram sem ter participado de nenhuma cirurgia. A complicação mais frequente foi a fratura do enxerto. A dificuldade técnica mais frequente foi o posicionamento dos parafusos. Imobilização no pós-operatório é a preferência da maioria dos participantes, que consideram fundamental a consolidação do enxerto para o retorno ao esporte. O maior número de complicações ocorreu com especialistas que obtiveram o título de 11 a 15 anos atrás. A região Sudeste é a maior formadora de especialistas e onde está concentrada a maior parte deles.


Asunto(s)
Humanos , Complicaciones Posoperatorias , Luxación del Hombro/terapia , Articulación del Hombro/cirugía , Brasil , Metaanálisis como Asunto , Inestabilidad de la Articulación/cirugía
18.
Parasitol Int ; 97: 102796, 2023 Dec.
Artículo en Inglés | MEDLINE | ID: mdl-37595832

RESUMEN

Myxozoans of Ceratomyxidae Doflein, 1899 are common coelozoic parasites of marine life, and are also found less frequently in freshwater fish. The present study describes Ceratomyxa ranunculiformis n. sp. as a new freshwater myxosporean species infecting the gall bladder of the Amazonian sciaenid Plagioscion squamosissimus. The new Ceratomyxa was described based on its host, myxospore morphology, ribosomal rDNA gene sequencing, parasite distribution, and phylogenetic analysis. Immature and mature plasmodia were tadpole-shaped or pyriform, and exhibited slow undulatory motility. The myxospores were elongated and crescent-shaped in the frontal view, with a sutural line between two valves, which had rounded ends. The measurements of the formalin-fixed myxospores were: average length 4.9 (4.0-6.6) µm, average thickness 37.6 (32.4-43.9) µm, average posterior angle 165° (154°-173°). Two ovoid polar capsules of equal size, average length 2.0 (1.4-3.0) µm and average width 1.9 (1.4-2.4) µm, were located adjacent to the suture and contained polar filaments with 2-3 coils. The integrated comparative analysis of the morphological characteristics and molecular analyses of the ribosomal rDNA genes supported the identification of a new species of coelozoic Ceratomyxa. Maximum likelihood analyses showed the new species clustering within a well-supported clade, together with all the other Amazonian freshwater ceratomyxids.


Asunto(s)
Myxozoa , Animales , Myxozoa/genética , Brasil , Filogenia , Peces , ADN Ribosómico/genética , Agua Dulce
19.
Anal Methods ; 15(29): 3499-3509, 2023 07 27.
Artículo en Inglés | MEDLINE | ID: mdl-37401176

RESUMEN

Considering the great economic significance of Coffea arabica (arabica) associated with the lower production cost of C. canephora (conilon), blends of these coffees are commercially available to reduce costs and combine sensory attributes. Thus, analytical tools are required to ensure consistency between real and labeled compositions. In this sense, chromatographic methods based on volatile analysis using static headspace-gas chromatography-mass spectrometry (SHS-GC-MS) and Fourier transform infrared (FTIR) spectroscopy associated with chemometric tools were proposed for the identification and quantification of arabica and conilon blends. The peak integration from the total ion chromatogram (TIC) and extracted ion chromatogram (EIC) was compared in multivariate and univariate scenarios. The optimized partial least squares (PLS) models with uninformative variable elimination (UVE) and chromatographic data (TIC and EIC) have similar accuracy according to a randomized test, with prediction errors between 3.3% and 4.7% and Rp2 > 0.98. There was no difference between the univariate models for the TIC and EIC, but the FTIR model presented a lower performance than GC-MS. The multivariate and univariate models based on chromatographic data had similar accuracy. For the classification models, the FTIR, TIC, and EIC data presented accuracies from 96% to 100% and error rates from 0% to 5%. Multivariate and univariate analyses combined with chromatographic and spectroscopic data allow the investigation of coffee blends.


Asunto(s)
Coffea , Coffea/química , Cromatografía de Gases y Espectrometría de Masas , Café/química , Análisis de los Mínimos Cuadrados , Espectroscopía Infrarroja por Transformada de Fourier
20.
Antioxidants (Basel) ; 12(6)2023 Jun 11.
Artículo en Inglés | MEDLINE | ID: mdl-37371988

RESUMEN

This study investigates the role of eugenol (EUG) on CS-induced acute lung injury (ALI) and how this compound is able to modulate macrophage activity. C57BL/6 mice were exposed to 12 cigarettes/day/5days and treated 15 min/day/5days with EUG. Rat alveolar macrophages (RAMs) were exposed to CSE (5%) and treated with EUG. In vivo, EUG reduced morphological changes inflammatory cells, oxidative stress markers, while, in vitro, it induced balance in the oxidative stress and reduced the pro-inflammatory cytokine release while increasing the anti-inflammatory one. These results suggest that eugenol reduced CS-induced ALI and acted as a modulator of macrophage activity.

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