RESUMEN
Objective: This research is based on the treatment of petroleum wastewater (PWW) with pretreated activated sludge for the production of electricity and removal of chemical oxygen demand (COD) using microbial fuel cell (MFC). Methods: The application of the MFC system which uses activated sludge biomass (ASB) as a substrate resulted in the reduction of COD by 89.5% of the original value. It generated electricity equivalent to 8.18 mA/m2 which can be reused again. This would solve the majority of environmental crises which we are facing today. Results: This study discusses the application of ASB to enhance the degradation of PWW for the production of a power density of 1012.95 mW/m2 when a voltage of 0.75 V (voltage) is applied at 30:70% of ASB when MFC is operated in a continuous mode. Microbial biomass growth was catalyzed using activated sludge biomass. The growth of microbes was observed by scanning through an electron microscope. Through oxidation in the MFC system, bioelectricity is generated which is used in the cathode chamber. Furthermore, the MFC operated using ASB in a ratio of 35 with the current density, which decreased to 494.76 mW/m2 at 10% ASB. Application: Our experiments demonstrate that the efficiency of the MFC system can generate bioelectricity and treat petroleum wastewater by using activated sludge biomass.
RESUMEN
Waste tyres were pyrolysed in a bench scale reactor and the product chars were chemically activated with alkali chemical agents, KOH, K2CO3, NaOH and Na2CO3 to produce waste tyre derived activated carbons. The activated carbon products were then examined in terms of their ability to adsorb NOx (NO) at low temperature (25°C) from a simulated industrial process flue gas. This study investigates the influence of surface area and porosity of the carbons produced with the different alkali chemical activating agents on NO capture from the simulated flue gas. The influence of varying the chemical activation conditions on the porous texture and corresponding NO removal from the flue gas was studied. The activated carbon sorbents were characterized in relation to BET surface area, micropore and mesopore volumes and chemical composition. The highest NO removal efficiency for the waste tyre derived activated carbons was â¼75% which was obtained with the adsorbent treated with KOH which correlated with both the highest BET surface area and largest micropore volume. In contrast, the waste tyre derived activated carbons prepared using K2CO3, NaOH and Na2CO3 alkali activating agents appeared to have little influence on NO removal from the flue gases. The results suggest problematic waste tyres, have the potential to be converted to activated carbons with NOx removal efficiency comparable with conventionally produced carbons.
Asunto(s)
Contaminantes Atmosféricos/química , Contaminación del Aire/prevención & control , Carbón Orgánico/análisis , Óxidos de Nitrógeno/química , Goma , Administración de Residuos/métodos , Adsorción , Frío , Eliminación de Residuos/economía , Residuos Sólidos/análisis , Administración de Residuos/economíaRESUMEN
Chars produced from the pyrolysis of different waste materials have been investigated in terms of their use as a catalyst for the catalytic cracking of biomass pyrolysis gases during the two-stage pyrolysis-gasification of biomass. The chars were produced from the pyrolysis of waste tyres, refused derived fuel and biomass in the form of date stones. The results showed that the hydrocarbon tar yields decreased significantly with all the char materials used in comparison to the non-char catalytic experiments. For example, at a cracking temperature of 800°C, the total product hydrocarbon tar yield decreased by 70% with tyre char, 50% with RDF char and 9% with biomass date stones char compared to that without char. There was a consequent increase in total gas yield. Analysis of the tar composition showed that the content of phenolic compounds decreased and polycyclic aromatic hydrocarbons increased in the product tar at higher char temperatures.