RESUMEN
In the title compound, C(12)H(14)N(2)OS, the pyrrolidine ring adopts an envelope conformation with the C atom at the 3-position as the flap and makes a dihedral angle of 65.80â (9)° with the benzene ring. In the crystal, N-Hâ¯O hydrogen bonds join c-glide related mol-ecules into chains extended along [001] that are further connected into (100) layers via C-Hâ¯O inter-actions.
RESUMEN
In the title compound, C(13)H(18)N(2)O(2)S, the 4-meth-oxy-benzoyl fragment is approximately planar [maximum deviation = 0.057â (2)â Å] and twisted relative to the thio-amide fragment, forming a dihedral angle of 86.62â (6)°. The two Csp(2)-Nsp(2) bonds in the thio-urea unit differ significantly in length [1.327â (2) and 1.431â (2)â Å]. In the crystal, N-Hâ¯O hydrogen bonds link the mol-ecules into chains parallel to [010].
RESUMEN
In the title compound, C(15)H(19)ClN(2)OS, the dihedral angle between the amide and thio-urea fragments is 58.07â (17)°. The cyclo-hexane group adopts a chair conformation and is twisted relative to the thio-urea fragment, forming a dihedral angle of 87.32â (18)°. In the crystal, N-Hâ¯S hydrogen bond links the mol-ecules into chains running parallel to the a-axis direction.
RESUMEN
In the title compound, C(11)H(13)N(3)O(3)S, the benzene ring is twisted relative to the amidic fragment, forming a dihedral angle of 27.26â (9)°. The thiono and carbonyl groups are trans with respect to the C-N bond. Inter-molecular N-Hâ¯S and C-Hâ¯O hydrogen bonds link the mol-ecules in the crystal structure.
RESUMEN
In the title compound, C(16)H(16)N(2)OS, the conformation at the two partially double C-N bonds of the thio-urea unit is E. The amide group is twisted relative to the thio-urea fragment, forming a dihedral angle of 62.44â (16)°, and the two phenyl rings form a dihedral angle 75.93â (18)°. In the crystal, mol-ecules are linked by N-Hâ¯S hydrogen bonds, forming centrosymmetric dimers.
RESUMEN
In the title compound, C(13)H(16)N(2)OS, the piperidine ring exhibit a classical chair conformation. In the crystal, the mol-ecules are linked by N-Hâ¯O hydrogen bonds, forming zigzag chains running parallel to the c axis.
RESUMEN
In the title compound, C(14)H(12)N(2)O(2)S, the amino-phenol and the benzoyl groups adopt a syn-anti configuration with respect to the thiono C=S group across the thio-urea C-N. The dihedral angle between the mean planes of the benzoyl and hy-droxy-phenyl rings is 36.77â (8)°. The mol-ecules are stabilized by intra-molecular N-Hâ¯O hydrogen bonds. In the crystal, weak inter-molecular C-Hâ¯O, O-Hâ¯S and N-Hâ¯O hydrogen bonds link the mol-ecules into a chain along the c axis.