RESUMEN
A highly responsive, discerning, and uncomplicated technique has been devised for immobilizing reagents onto a plasticizer-free optical sensor membrane, employing polymer inclusion membranes (PIMs). This procedural strategy relies on a physical immobilization approach, specifically encapsulation, resulting in the creation of an optical sensing membrane. The responsive PIM is composed of poly(vinyl chloride) (PVC) as the fundamental polymer, Aliquat 336 as an extractant, and 4-(4 -chlorobenzylideneimino)-3-methyl-5-mercapto-1,2,4-triazole (CBIMMT) as the reagent. The optimized sensor demonstrates a linear range of 6.00-156 ng/mL for Te(IV), along with detection and quantification limits of 1.75 and 5.60 ng/mL, respectively. The sensor response time is 3.0 min, confirming its reproducibility. Effective regeneration of the sensor is achieved using a 0.2 mol/L HCl solution. The sensor membrane's selectivity is evaluated against various interfering ions, underscoring minimal interference. The sensor membrane efficacy is demonstrated through successful applications in quantifying Te(IV) levels, including natural water, chalcogenides, milk, vegetables, and soil samples.
Asunto(s)
Polímeros , Telurio , Plastificantes , Reproducibilidad de los Resultados , Agua , Indicadores y ReactivosRESUMEN
A novel optical sensor has been developed to measure selenium ions. The sensor membrane was created by mixing xylenol orange (XO) and sodium tetraphenylborate (NaTPB) with a plasticized poly(vinyl chloride) membrane that contained o-nitrophenyl octyl ether (o-NPOE) as a plasticizer. XO was previously established for use in a colorimeter to measure selenium in water and other media. At pH 6.6, the color of the detecting membrane changed from orange to pink when in contact with Se4+ ions. Various variables affecting the uptake efficiency were evaluated and optimized. Under optimum conditions (i.e., 30% PVC, 60% o-NPOE, and 5.0% of both XO and NaTPB for 5.0 min as the response time), the proposed sensor displayed a linear range 10-175 ng mL-1 with the detection and quantification limits of 3.0 and 10 ng mL-1, respectively. Also, the precision (RSD%) was better than 2.2% for six replicate determinations of 100 ng mL-1 Se4+ in various membranes. For the detection of Se4+, the selectivity of the sensor membrane was investigated for a number of possible interfering inorganic cations, but no appreciable interference was found. With the use of a 0.3 M HCl solution, the sensor was successfully restored, and the response that may have been reversible and reproducible exhibited an RSD% of less than 2.0%. The sensor has been successfully used to analyze Se4+ ions in environmental and biological materials.
RESUMEN
An optical chemical sensor has been developed for the quantitative spectrophotometric analysis of copper. The optode is dependent on covalent immobilization of 2-(2-benzothiazolylazo)-3-hydroxyphenol (BTAHP) in a transparent agarose membrane. The absorbance variation of immobilized BTAHP on agarose as a film upon the addition of 5 × 10-3 M aqueous solutions of Mn2+, Zn2+, Hg2+, Cd2+, Pb2+, Co2+, Ni2+, Fe2+, La3+, Fe3+, Cr3+, Zr4+, Se4+, Th4+, and UO22+ revealed substantially higher changes in the Cu2+ ion content compared to other ions investigated here. The effects of various experimental parameters, such as the solution pH, the reaction time, and the concentration of reagents, on the quality of Cu2+ sensing were examined. Under ideal experimental circumstances, a linear response was achieved for Cu2+ concentrations ranging from 1.0 × 10-9 to 7.5 × 10-6 M with an R2 value of 0.9988. The detection (3σ) and quantification (10σ) limits of the procedure for Cu2+ analyses were 3.0 × 10-10 and 9.8 × 10-10 M, respectively. No observable interference was recorded in the detection of Cu2+ due to other inorganic cations. With no indication of BTAHP leaching, the membrane demonstrated good durability and quick response times. The optode was effectively used to determine the presence of Cu2+ in environmental water, food, and biological samples.