RESUMEN

Phosphorous (P) removal in wastewater treatment is essential to prevent eutrophication in water bodies. Side-stream enhanced biological phosphorous removal (S2EBPR) is utilized to improve biological P removal by recirculating internal streams within a side-stream reactor to generate biodegradable carbon (C) for polyphosphate accumulating organisms (PAOs). In this study, a full-scale S2EBPR system in a water resource recovery facility (WRRF) was evaluated for 5 months. Batch experiments revealed a strong positive correlation (r = 0.91) between temperature and C consumption rate (3.56-8.18 mg-COD/g-VSS/h) in the system, with temperature ranging from 14°C to 18°C. The anaerobic P-release to COD-uptake ratio decreased from 0.93 to 0.25 mg-P/mg-COD as the temperature increased, suggesting competition between PAOs and other C-consumers, such as heterotrophic microorganisms, to uptake bioavailable C. Microbial community analysis did not show a strong relationship between abundance and activity of PAO in the tested WRRF. An assessment of the economic feasibility was performed to compare the costs and benefits of a full scale WRRF with and without implementation of the S2EBPR technology. The results showed the higher capital costs required for S2EBPR were estimated to be compensated after 5 and 11 years of operation, respectively, compared to chemical precipitation and conventional EBPR. The results from this study can assist in the decision-making process for upgrading a conventional EBPR or chemical P removal process to S2EBPR. PRACTITIONER POINTS: Implementation of S2EBPR presents adaptable configurations, exhibiting advantages over conventional setups in addressing prevalent challenges associated with phosphorous removal. A full-scale S2EBPR WRRF was monitored over 5 months, and activity tests were used to measure the kinetic parameters. The seasonal changes impact the kinetic parameters of PAOs in the S2EBPR process, with elevated temperatures raising the carbon demand. PAOs abundance showed no strong correlation with their activity in the full-scale S2EBPR process in the tested WRRF. Feasibility assessment shows that the benefits from S2EBPR operation can offset upgrading costs from conventional BPR or chemical precipitation.

Asunto(s)

Reactores Biológicos , Polifosfatos , Fósforo , Cinética , Carbono

RESUMEN

This work investigated the impact of a waste-derived carbon source, crude glycerol (CG), on Anammox. Batch bioassays were conducted to identify inhibitory component(s) in CG, and the relationship between Anammox activity and the concentration of CG, pure glycerol, and methanol were assessed. The results showed that the half-maximal inhibitory concentration of CG and methanol are 434.5 ± 51.8 and 143.0 ± 19.6 mg chemical oxygen demand (COD) L-1, respectively, while pure glycerol at 0-2283 mg COD L-1 had no significant adverse effect on Anammox. The results suggested methanol is the major inhibitor in CG via a non-competitive inhibition mechanism. COD/total inorganic nitrogen ratio of > 1.3 was observed to cause a significant Anammox inhibition (>20 %), especially at low substrate level. These results are valuable for evaluating the feasibility of using CG for nitrogen removal in water resource recovery facilities, promoting sustainable development.

Asunto(s)

Compuestos de Amonio , Purificación del Agua , Glicerol , Desnitrificación , Anaerobiosis , Oxidación Anaeróbica del Amoníaco , Metanol , Oxidación-Reducción , Reactores Biológicos , Nitrógeno/análisis , Aguas del Alcantarillado

RESUMEN

Plastic debris as the main portion of urban litters could be transported via storm runoff to the water resources. In this study the influence of microplastics (MPs) weathering on their Pb2+ and Zn2+ uptake in stormwater was examined. Low-density polyethylene (LDPE) and polyethylene terephthalate (PET) MPs were subjected to weathering through mechanical interaction with a mixture of silt/sand, and in synthetic stormwater. The surface analysis revealed significant physio-chemistry alterations of LDPE MPs due to the silt/sand weathering. However, this weathering mostly resulted in the surface morphology alterations of PET MPs. The kinetics of heavy metals adsorptions onto the new and stormwater weathered LDPE MPs were best described by pseudo 1st and 2nd models, respectively. Despite increasing Pb2+ uptake by weathered PET MPs, Zn2+ uptake by both new and weathered PET MPs was below the detection limit. Both Pb2+ and Zn2+ were released from new and silt/sand weathered LDPE MPs during five days exposure to the synthetic stormwater. This study underscores the critical role of plastic type and weathering conditions on heavy metal transport by MPs from the urban environment to the water resources.