RESUMEN
Minimizing the impact of electromagnetic radiation (EMR) holds paramount importance in safeguarding individuals who frequently utilize electrical and electronic devices. Electrically conductive textiles, which possess specialized EMR shielding features, present a promising solution to mitigate the risks related to EMR. Furthermore, these textile-based shielding materials could find application as radar-absorbing materials in stealth technology, emphasizing the need for substantial absorption capabilities in shielding mechanisms. In this study, various textile-based materials with an electrically conductive coating that contain the conjugated polymer system poly(3,4-ethylene-dioxythiophene)-polystyrene sulfonate (PEDOT:PSS) were prepared and investigated. The influence of the textile substrate structural parameters, coating deposit, and coating method on their microwave properties-transmission, reflection, and absorption-was investigated. Reflection and transmission measurements were conducted within a frequency range of 2 to 18 GHz. These measurements revealed that, for the tested samples, the shielding properties are determined by the combined effect of reflection and absorption. However, the role of these two parameters varies across the tested frequency range. It was defined that for fabrics coated on one side, better reflection reduction is obtained when the shielding effectiveness (SE) is below |20| dB. It was found that by controlling the coating deposition on the fabric, it is possible to fine-tune the electrical properties to a certain extent, thereby influencing the microwave properties of the coated fabrics. The studies of prepared samples have shown that reflection and transmission parameters depend not only on the type and quantity of conductive paste applied to the fabric but also on the fabric's construction parameters and the coating technique used. It was found that the denser the substrate used for coating, the more conductive paste solidifies on the surface, forming a thicker coat on the top. For conductive fabrics with the same substrate to achieve a particular SE value using the knife-over-roll coating technology, the required coating deposit amount is considerably lower as compared with the deposit necessary in the case of screen printing: for the knife-over-roll-coated sample to reach SE 15 dB, the required deposit is approximately 14 g/m2; meanwhile, for a sample coated via screen printing, this amount rises to 23 g/m2.
RESUMEN
The way to improve the properties (resistance to washing, delamination, and rubbing off) of the PEDOT:PSS coating applied on wool fabric without reduction of its electrical conductivity by introducing a commercially available combination of low formaldehyde content melamine resins into the printing paste is presented in this paper. Primarily, to improve the hydrophilicity and dyeability of wool fabric, the samples were modified using low-pressure nitrogen (N2) gas plasma. Two commercially available PEDOT:PSS dispersions were used to treat wool fabric by the exhaust dyeing and screen printing methods, respectively. Spectrophotometric measurements of the color difference (ΔE*ab) and visual evaluation of woolen fabric dyed and printed with PEDOT:PSS in different shades of the blue color showed that the sample modified with N2 plasma obtained a more intense color compared to the unmodified one. SEM was used to examine the surface morphology and a cross-sectional view of wool fabric that had undergone various modifications. SEM image shows that the dye penetrates deeper into the wool fabric after plasma modification using dyeing and coating methods with a PEDOT:PSS polymer. In addition, with a Tubicoat fixing agent, HT coating looks more homogeneous and uniform. The chemical structure spectra of wool fabrics coated with PEDOT:PSS were investigated using FTIR-ATR characterization. The influence of melamine formaldehyde resins on the electrical properties, resistance to washing, and mechanical effects of PEDOT:PSS treated wool fabric was also evaluated. The resistivity measurement of the samples containing melamine-formaldehyde resins as an additive did not show a significant decrease in electrical conductivity, while the electrical conductivity was maintained after the washing and rubbing test as well. The best results of electrical conductivity for investigated wool fabrics before and after washing and mechanical action were determined for samples subjected to the combined processing-surface modification by low-pressure N2 plasma, dyeing by exhaust with PEDOT:PSS, and coating by the screen-printing method of PEDOT:PSS and a 3 wt.% melamine formaldehyde resins mixture.
RESUMEN
The influence of different concentrations of salt-added polyethylene oxide (PEO) on the spinnability of chitosan (CS)/PEO + NaCl blends that could be used as a component part of filters for water treatment or nanofiber membranes as well as for medical applications was investigated in this study. The morphological properties of manufactured nanofibers were analyzed as well. It was determined that an increase of PEO concentration resulted mostly in thin and round nanofibers formed during electrospinning, but the manufacturing process became complex, because many wet fibers reached the collector while spinning. Also, it was noticed that the salt was not dissolved completely in the polymer solutions and some crystals were seen in the SEM images of manufactured fiber mats. However, the addition of salt resulted in lower viscosity and better conductivity of solution and fiber mats as well. The opposite effect was observed as the concentration of PEO was increased. The orientation of produced nanofibers as well as their diameter were analyzed with commercially available software. It was determined that the results obtained by software and microscopically are repeatable. The difference among the results of diameter calculated with software and taken by microscope varied from 0% to approximately 12%. The FTIR analyses indicated that alterations in polymer concentrations or the addition of salt did not induce any discernible changes in the chemical composition or nature of the materials under investigation. The sodium chloride present in the solutions enhanced electrical properties and increased conductivity values more than 50 times for PEO solutions and six times for CS/PEO blend solutions, compared to conductivity values of solutions without salt. To assess the thermal characteristics of the PEO/CS blend nanofibers, measurements using a differential scanning calorimeter (DSC) to determine melting (Tm) and crystallization (Tc) temperatures, as well as specific heat capacities were conducted. These parameters were derived from the analysis of endothermic and exothermic peaks observed in the DSC data. It showed that all produced nanofibers were semicrystalline.
RESUMEN
This study presents the effect of non-thermal plasma modification on the changes of surface morphology, color characteristics and electrical conductivity of wool fabric dyed with intrinsically conductive polymer (ICP) poly (3,4-ethylenedioxythiophene) polystyrene sulfonate (PEDOT: PSS). The wool fabric was treated with an aqueous dispersion of PEDOT: PSS, Clevios F ET, providing electrically conductive properties to textiles. The wool fabric, containing basic groups of amines (NH2), was pre-activated with low-pressure plasma of non-polymer forming nitrogen (N2) gas before exhaust dyeing with PEDOT: PSS at 90 °C was applied. This treatment imparted hydrophilicity, reduced felting, increased adhesion, improved dye ability and ensured that more PEDOT: PSS negatively charged sulfonate (-SO3-) counter ions would be electrostatically bounded with the cationic protonated amine groups of the wool fiber. Initially, before (N2) plasma treatment and after fabrics were evaluated according to the test method for aqueous liquid repellency, the surface morphology of the plasma-modified and -unmodified wool dyed fabric was observed with scanning electron microscopy (SEM). The functional groups introduced onto the surface after N2 gas plasma treatment of wool fabric were characterized by X-ray photoelectron and FTIR-ATR spectroscopy. The results of color difference measurements show that N2 gas plasma treatments provide more intense color on Clevios F ET dyed wool fabric and retain its electrical conductivity.
RESUMEN
Socks are an important part of our clothing used in everyday activities. In order to ensure thermal comfort during wear in cool outdoor or indoor conditions, and for health improvement, socks must have effective thermoregulation properties. Chemical far-infrared (FIR) fibers with different bio-ceramic compounds incorporated into socks' structures can provide an improved thermoregulation effect to the wearer of the socks. Fibers with silver and carbon additives incorporated in their structures can also affect the thermoregulation properties of socks. Moreover, these conductive additives avoid the unpleasant effect of static electricity of socks. The main parts of the different investigated structures of the socks were made in a plush pattern. The plush loops were formed by using functional Resistex® Bioceramic, Shieldex® and two modifications of Nega-Stat® fiber yarns. The main thermal comfort (thermal efficiency, microclimate and heat exchange temperatures, thermal resistance, water vapor permeability) and electrostatic (surface and vertical resistances, shielding factor, half time decay of charge) properties of the socks were investigated. Based on the obtained results of the thermal comfort and electrostatic characteristics of the different investigated structures of socks, the optimal static dissipative (half-time decay <0.01 s, shielding factor0.96) plush knitting structure with 55% Resistex® Bioceramic and 31% bicomponent Nega-Stat® P210 fibers yarns was selected. Comparing the control sample without FIR and the knitted structure with conductive additives, we can draw the conclusion that the heat retention capability of the selected socks was improved by 1.5 °C and the temperature of their created microclimate was improved by 2 °C.
RESUMEN
The most important functional purpose of knitted fabrics used for the protective non-flammable underwear worn in contact with the skin is to ensure wearing comfort by creating and maintaining a constant and pleasant microclimate at the skin surface independently from the environmental conditions. Protective non-flammable underwear may be used by firefighters or sportsmen, e.g., racing (Formula) sportsmen, where a risk of burn injuries (when the car is on fire after a car crash) is present. In order to investigate the flammability and thermal comfort properties of two-layer knitted fabrics, two groups of aramids and flame-retardant (FR) viscose fiber fabrics of different combined patterns and surface structures (porosity and flatness) were designed and manufactured for this research. Aramid fiber spun yarns (METAFINE.X.95®) formed the inner layer (contacting with human skin) of fabrics and aramid/viscose FR fiber spun yarns (METALEN®) formed the outer layer. For the evaluation of the functional characteristics of the manufactured fabrics, the flammability and thermoregulating properties, such as liquid moisture management, water vapor and air permeability, and thermal resistance were investigated. The results show that all tested fabrics are non-flammable, breathable, permeable to air, and can be assigned to moisture management fabrics. Their obtained overall moisture management capacity (OMMC) values are in the range 0.59-0.88. The knitted fabrics with an embossed porous surface to skin had a higher OMMC (0.75-0.88). The thermoregulation comfort properties were mostly influenced by the structure of the fabrics, while the burning behavior was found to be independent from the structure, and the non-flammability properties were imparted by the fiber content of the knits.
RESUMEN
Phase changing materials (PCMs) microcapsules MPCM32D, consisting of a polymeric melamine-formaldehyde (MF) resin shell surrounding a paraffin core (melting point: 30-32 °C), have been modified by introducing thermally conductive additives on their outer shell surface. As additives, multiwall carbon nanotubes (MWCNTs) and poly (3,4-ethylenedioxyoxythiophene) poly (styrene sulphonate) (PEDOT: PSS) were used in different parts by weight (1 wt.%, 5 wt.%, and 10 wt.%). The main aim of this modification-to enhance the thermal performance of the microencapsulated PCMs intended for textile applications. The morphologic analysis of the newly formed coating of MWCNTs or PEDOT: PSS microcapsules shell was observed by SEM. The heat storage and release capacity were evaluated by changing microcapsules MPCM32D shell modification. In order to evaluate the influence of the modified MF outer shell on the thermal properties of paraffin PCM, a thermal conductivity coefficient (λ) of these unmodified and shell-modified microcapsules was also measured by the comparative method. Based on the identified optimal parameters of the thermal performance of the tested PCM microcapsules, a 3D warp-knitted spacer fabric from PET was treated with a composition containing 5 wt.% MWCNTs or 5 wt.% PEDOT: PSS shell-modified microcapsules MPCM32D and acrylic resin binder. To assess the dynamic thermal behaviour of the treated fabric samples, an IR heating source and IR camera were used. The fabric with 5 wt.% MWCNTs or 5 wt.% PEDOT: PSS in shell-modified paraffin microcapsules MPCM32D revealed much faster heating and significantly slower cooling compared to the fabric treated with the unmodified ones. The thermal conductivity of the investigated fabric samples with modified microcapsules MPCM32D has been improved in comparison to the fabric samples with unmodified ones. That confirms the positive influence of using thermally conductive enhancing additives for the heat transfer rate within the textile sample containing these modified paraffin PCM microcapsules.
RESUMEN
This study presents the investigation of the electromagnetic properties and resistance performance of electrically conductive fabrics coated with composition containing the conjugated polymer system poly(3,4-ethylenedioxythiophene)-polystyrene sulfonate (PEDOT:PSS). The developed fabrics were intended for electromagnetic radiation (EMR) shielding in microwave range and for absorbing microwaves in radar operating range, so as to act as radar absorbing materials (RAM). The measurements of reflection and transmission of the developed fabrics were performed in a frequency range of 2-18 GHz, which covers the defined frequencies relevant to the application. Four types of fabrics with different fiber composition (polyamide; polyamide/cotton; wool and para-aramid/viscose) were selected and coated with conductive paste using screen printing method. It was found that EMR shielding effectiveness (SE) as well as absorption properties depend not only the amount of conductive paste topped on the fabric, but also resides in the construction parameters of fabrics. Depending on such fabric structural parameters as density, mass per unit area, type of weave, a layer of shield (or coating) just sticks on the fabric surface or penetrates into fabric, changing the shield thickness and herewith turning SE results. Meanwhile, the fiber composition of fabrics influences mostly bonding between fibers and polymer coating. To improve the resistance performance of the developed samples, a conventional textile surface modification technique, atmospheric plasma treatment, was applied. Initially, before plasma treatment and after treatment the fabrics were evaluated regarding an aqueous liquid repellency test, measuring the contact angles for the water solvent. The influence of plasma treatment on resistance performance of coated fabrics was evaluated by subjecting the plasma treated samples and untreated samples to abrasion in the Martindale abrasion apparatus and to multiplex washing cycles. These investigations revealed that applied plasma treatment visibly improved abrasion resistance as a result of better adhesion of the coating. However, washing resistance increased not so considerably.
RESUMEN
The purpose of this study is to investigate the thermoregulatory properties of polyethylene terephthalate (PET) 3D knitted materials with bioceramic additives which are highly absorbing far-infrared (FIR) radiation. Ceramic materials are well-known and useful for thermal insulation applications. In order to compare different types of ceramic additives and coating methods for their incorporation into textile, several types of ceramic compounds with heat-retaining function were selected: germanium (Ge), aluminum (Al) and silicon (Si) additives were applied by impregnation in squeezing padder and titanium (Ti) by the screen printing method. The thermoregulatory properties (thermal resistance, heat-retaining effectiveness and air permeability) of 3D PET knits with bioceramic additives were estimated. In this study scanning electron microscopy (SEM) images were used to analyze the morphology of coated fabrics, X-ray fluorescence spectroscopy (XRF) analysis was applied to evaluate the number of minerals with high heat capacity in each formulation used for treatment. The knits coated with a formulation containing Ti ceramic additives demonstrated the most effective thermal behavior. Furthermore, better heat accumulation effectiveness of Ti ceramics containing knits was confirmed by Fourier transform infrared spectroscopy (FTIR) analysis. It was also determined that 3D knitted fabric with Ti ceramic additives showed the highest emissivity among tested samples and the implication is that this sample radiates its energy more efficiently than others.