RESUMEN
We present a multi-species trace gas sensor based on a fast, compact home-built Fourier transform spectrometer (FTS) combined with a broadband mid-infrared supercontinuum (SC) source. The spectrometer covers the spectral bandwidth of the SC source (2 - 4 µm) and provides a best spectral resolution of 1 GHz in 6 seconds. It has a detection sensitivity of a few hundred of ppbv Hz-1/2 for different gas species. We study the performance of the developed spectrometer in terms of precision, linearity, long-term stability, and multi-species detection. We use the spectrometer for measuring fruit-produced volatiles under different atmospheric conditions and compare the performance with a previously developed scanning grating-based spectrometer.
Asunto(s)
Gases/análisis , Malus/química , Malus/fisiología , Espectroscopía Infrarroja por Transformada de Fourier/instrumentación , Acetaldehído/análisis , Acetatos/análisis , Acetona/análisis , Diseño de Equipo , Etano/análisis , Etanol/análisis , Etilenos/análisis , Análisis de Fourier , Metanol/análisis , Espectroscopía Infrarroja por Transformada de Fourier/métodosRESUMEN
Conventional mechanical Fourier Transform Spectrometers (FTS) can simultaneously measure absorption and dispersion spectra of gas-phase samples. However, they usually need very long measurement times to achieve time-resolved spectra with a good spectral and temporal resolution. Here, we present a mid-infrared dual-comb-based FTS in an asymmetric configuration, providing broadband absorption and dispersion spectra with a spectral resolution of 5 GHz (0.18 nm at a wavelength of 3333 nm), a temporal resolution of 20 µs, a total wavelength coverage over 300 cm-1 and a total measurement time of ~70 s. We used the dual-comb spectrometer to monitor the reaction dynamics of methane and ethane in an electrical plasma discharge. We observed ethane/methane formation as a recombination reaction of hydrocarbon radicals in the discharge in various static and dynamic conditions. The results demonstrate a new analytical approach for measuring fast molecular absorption and dispersion changes and monitoring the fast dynamics of chemical reactions over a broad wavelength range, which can be interesting for chemical kinetic research, particularly for the combustion and plasma analysis community.
RESUMEN
We present a multi-species trace gas sensor based on a high-repetition-rate mid-infrared supercontinuum source, in combination with a 30 m multipass absorption cell, and a scanning grating spectrometer. The output of the spectrometer is demodulated by a digital lock-in amplifier, referenced to the repetition rate of the supercontinuum source. This improved the detection sensitivity of the system by a factor 5, as compared to direct baseband operation. The spectrometer provides a spectral coverage of 950 cm-1 (between 2.85-3.90 µm) with a resolution of 2.5 cm-1 in 100 ms. It can achieve noise equivalent detection limits in the order of 100 ppbv Hz-1/2 for various hydrocarbons, alcohols, and aldehydes.